Heterometallic Au(I)–Cu(I) Clusters : Luminescence Studies and 1O2 Production
Romo-Islas, G., Ward, J. S., Rissanen, K., & Rodríguez, L. (2023). Heterometallic Au(I)–Cu(I) Clusters : Luminescence Studies and 1O2 Production. Inorganic Chemistry, 62(21), 8101-8111. https://doi.org/10.1021/acs.inorgchem.3c00046
Julkaistu sarjassa
Inorganic ChemistryPäivämäärä
2023Tekijänoikeudet
© The Authors. Published by American Chemical Society
Two different organometallic gold(I) compounds containing naphthalene and phenanthrene as fluorophores and 2-pyridyldiphenylphosphane as the ancillary ligand were synthesized (compounds 1 with naphthalene and 2 with phenanthrene). They were reacted with three different copper(I) salts with different counterions (PF6–, OTf–, and BF4–; OTf = triflate) to obtain six Au(I)/Cu(I) heterometallic clusters (compounds 1a–c for naphthalene derivatives and 2a–c for phenanthrene derivatives). The heterometallic compounds present red pure room-temperature phosphorescence in both solution, the solid state, and air-equilibrated samples, as a difference with the dual emission recorded for the gold(I) precursors 1 and 2. The presence of Au(I)–Cu(I) metallophilic contacts has been identified using single-crystal X-ray diffraction structure resolution of two of the compounds, which play a direct role in the resulting red-shifted emission with respect to the gold(I) homometallic precursors. Polystyrene (PS) and poly(methyl methacrylate) (PMMA) polymeric matrices were doped with our luminescent compounds, and the resulting changes in their emissive properties were analyzed and compared with those previously recorded in the solution and the solid state. All complexes were tested to analyze their ability to produce 1O2 and present very good values of ΦΔ up to 50%.
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American Chemical Society (ACS)ISSN Hae Julkaisufoorumista
0020-1669Asiasanat
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https://converis.jyu.fi/converis/portal/detail/Publication/183226809
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The authors are grateful to Project PID2019-104121GB-I00 funded by the Ministerio de Ciencia e Innovación of Spain MCIN/AEI/10.13039/501100011033. G.R.-I. acknowledges Fundación Carolina and Secretaría de Relaciones Exteriores de México for the Ph.D. Scholarship.Lisenssi
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