Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer
Abstract
The aim of this work is to develop a novel π-coordination compound with unusual architecture using allylcytisine (Acyt) as a suitable scaffold. The synthesis and structural characterization of {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] (1) and Acyt itself have been performed, accompanied by quantum chemical studies. A distinctive feature of structure 1 is the formation of H-bonded pairs of two {Acyt(H+)} cations, showing the non-equivalent participation of its allyl group regarding to Cu+ coordination, thus forcing the organization of the acentric structure 1 with the unusually organized anionic copper(I) halide 1D-coordination polymer.
Main Authors
Format
Articles
Research article
Published
2022
Series
Subjects
Publication in research information system
Publisher
Elsevier BV
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-202303222244Käytä tätä linkitykseen.
Review status
Peer reviewed
ISSN
0277-5387
DOI
https://doi.org/10.1016/j.poly.2022.116022
Language
English
Published in
Polyhedron
Citation
- Slyvka, Y., Goreshnik, E., Pokhodylo, N., Morozov, D., Tupychak, M., & Mys'kiv, M. (2022). Allylcytisine as a convenient scaffold for the construction of the π,σ-coordination compound {Acyt(H+)}[Cu8{Acyt(H+)}Cl10] with the unusual anionic 1D-coordination polymer. Polyhedron, 224, Article 116022. https://doi.org/10.1016/j.poly.2022.116022
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Additional information about funding
The authors are grateful to the Ministry of Education and Science of Ukraine (Grant Nos. 0120U101622) and the Slovenian Research Agency (ARRS) within the research program P1–0045 Inorganic Chemistry and Technology for financial support. We also thank the CSC-IT centre in Espoo (Finland) for providing computational resources.
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