The solid-state hierarchy and iodination potential of [bis(3-acetaminopyridine)iodine(I)]PF6
Abstract
The first iodine(I) complex bearing hydrogen-bond donor and acceptor groups, [bis(3-acetaminopyridine)iodine(I)]PF6 (3), was synthesised, which exhibited two temperature-dependent solid-state connectivities of the hydrogen bonding. Upon reaction of 3 with tBuOMe, unprecedented iodination of a tBu methyl group proceeded under exceptionally mild conditions in good yield.
Main Author
Format
Articles
Research article
Published
2022
Series
Subjects
Publication in research information system
Publisher
Royal Society of Chemistry (RSC)
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-202301031052Use this for linking
Review status
Peer reviewed
ISSN
1466-8033
DOI
https://doi.org/10.1039/d2ce01225a
Language
English
Published in
CrystEngComm
Citation
- Ward, J. S. (2022). The solid-state hierarchy and iodination potential of [bis(3-acetaminopyridine)iodine(I)]PF6. CrystEngComm, 24(40), 7029-7033. https://doi.org/10.1039/d2ce01225a
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Funder(s)
Research Council of Finland
Funding program(s)
Academy Research Fellow, AoF
Akatemiatutkija, SA
Additional information about funding
The author would like to acknowledge the Magnus Ehrnrooth Foundation and the University of Jyväskylä for funding this research.
Copyright© The Royal Society of Chemistry 2022