Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages
Abstract
Giant octahedral M32 coordination cages were prepared via self-assembly of sulfonylcalix[4]arene-supported tetranuclear M(II) clusters (M = Co, Ni) with hybrid linker based on tris(dipyrrinato)cobalt(III) complexes appended with peripherical carboxylic groups. Due to intrinsic and extrinsic porosity, the obtained solid-state supramolecular architectures demonstrated good performance as adsorbents for the separation of industrially important gases mixtures.
Main Authors
Format
Articles
Research article
Published
2022
Series
Subjects
Publication in research information system
Publisher
Royal Society of Chemistry (RSC)
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-202212135567Use this for linking
Review status
Peer reviewed
ISSN
1359-7345
DOI
https://doi.org/10.1039/d2cc04510a
Language
English
Published in
Chemical Communications
Citation
- Khariushin, I., Ovsyannikov, A., Baudron, S., Ward, J., Kiesilä, A., Rissanen, K., Kalenius, E., Kovalenko, K., Fedin, V., Solovieva, S., Antipin, I., Bulach, V., & Ferlay, S. (2022). Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages. Chemical Communications, 58(98), 13628-13631. https://doi.org/10.1039/d2cc04510a
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Funder(s)
Research Council of Finland
Funding program(s)
Academy Project, AoF
Akatemiahanke, SA
Additional information about funding
This work was supported by the University of Strasbourg, the Institute Universitaire de France, Doctoral Mechnikov scholarship from French Embassy (I. V. K.), the CNRS, the Russian Science Foundation (Project N° 19-73-20035 to I. V. K., A. S. O., S. E. S., I. S. A.), the Government assignment for Nikolaev Institute of RAS (K. A. K., V. P. F.). The authors are grateful to Kurchatov Complex For Synchrotron And Neutron Investigations for performing of XRD-analysis on powdered samples (Dr Roman D. Svetogorov), to Spectral-Analytical Center of FRC Kazan Scientific Center of RAS for their help and support in TGA (Dr Ayrat R. Khamatgalimov) and IR studies. The authors gratefully acknowledge the Magnus Ehrnrooth Foundation (J. S. W.), the Academy of Finland (K. R. grant N° 317259), and the University of Jyväskylä, Finland, for financial support.
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