The role of oxidation treatments before and after CVD synthesis of graphene on copper catalytic surface
Abstract
Graphene is a sheet of honeycomb bonded carbon, that is only one atom thick. Aside
from its remarkable strength, graphene has great conducting and photochemical prop erties. Due to its unique properties, it can be used as viable option for rare metals in
circuits and in new type of measuring components. To express these properties at their
best, graphene should be single crystal and as clean as possible.
In this bachelor thesis, different treatment options for catalytic metal surface for graphene
synthesis are studied in chemical vapor deposition growth. Different options to treat the
catalytic metal layer were studied, such as changes in gas compositions in annealing
process, electropolishing, plasma and UV-light treatment. All the processes effect the
oxidation level of the surface. Different catalytic metals can also lead to higher quality
graphene. Synthesised graphene can be cleaned from amorphous carbon by treating it
with carbon dioxide or changing the carbon precursor for the chemical vapor deposition
process.
In the experimental part, the effects of higher concentration of hydrogen during synthesis
was studied. Higher concentration of hydrogen led to lower nucleation density of graphene,
but the catalytic copper surface was damaged in these processes. After synthesis, anneal ing under carbon dioxide flow was studied as a means of cleaning the surface. It was
found to reduce amorphous carbon in the product but it increased the manifestation of
double layers.
Main Author
Format
Theses
Bachelor thesis
Published
2021
Subjects
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-202107054173Use this for linking
Language
English