An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide
Afanasenko, A. M., Bulatov, E., Chulkova, T. G., Haukka, M., & Dolgushin, F. M. (2016). An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide. Transition Metal Chemistry, 41(4), 387-392. https://doi.org/10.1007/s11243-016-0034-7
Published in
Transition Metal ChemistryAuthors
Date
2016Copyright
© 2016, Springer International Publishing Switzerland
The oxidation of (oxime)PtII species using the electrophilic chlorine-based oxidant N,N-dichlorotosylamide (4-CH3C6H4SO2NCl2) was studied. The reactions of trans-[PtCl2(oxime)2] (where oxime = acetoxime, cyclopentanone oxime, or acetaldoxime) with this oxidant led to trans-[PtCl4(oxime)2] products. The oxidation of trans-[Pt(o-OC6H4CH = NOH)2] at room temperature gave trans-[PtCl2(o-OC6H4CH = NOH)2], whereas the same reaction upon heating was accompanied by electrophilic substitution of the benzene rings.
Publisher
Springer International PublishingISSN Search the Publication Forum
0340-4285Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/25598941
Metadata
Show full item recordCollections
License
Related items
Showing items with similar title or keywords.
-
Room-Temperature Phosphorescence and Efficient Singlet Oxygen Production by Cyclometalated Pt(II) Complexes with Aromatic Alkynyl Ligands
Lázaro, Ariadna; Cunha, Carla; Bosque, Ramon; Pina, João; Ward, Jas S.; Truong, Khai-Nghi; Rissanen, Kari; Lima, João Carlos; Crespo, Margarita; Seixas de Melo, J. Sérgio; Rodríguez, Laura (American Chemical Society, 2020)The synthesis of five novel cyclometalated platinum(II) compounds containing five different alkynyl-chromophores was achieved by the reaction of the previously synthesized Pt–Cl cyclometalated compound (1) with the ... -
Removal of selected antibiotics and antiretroviral drugs during post‐treatment of municipal wastewater with UV, UV/chlorine and UV/hydrogen peroxide
Ngumba, Elijah; Gachanja, Anthony; Tuhkanen, Tuula (Wiley, 2020)Active pharmaceutical ingredients (APIs) are only partially removed by convectional wastewater treatment plants. This study aimed at assessing the post‐treatment degradation of selected antibiotics and antiretroviral drugs ... -
Supramolecular Assembly of Metal Complexes by (Aryl)I⋯dz2[PtII] Halogen Bond
Katlenok, Eugenе A.; Haukka, Matti; Levin, Oleg V.; Frontera, Antonio; Kukushkin, Vadim Yurievich (Wiley-VCH Verlag, 2020)The theoretical data for the half‐lantern complexes [Pt(C^N)(μ‐S^N)] 2 ( 1 – 3 ; С^N is cyclometalated 2‐Ph‐benzothiazole; S^N is 2‐SH‐pyridine 1 , 2‐SH‐benzoxazole 2 , 2‐SH‐tetrafluorobenzothiazole 3 ) indicate that the ... -
C,N-chelated diaminocarbene platinum(II) complexes derived from 3,4-diaryl-1H-pyrrol-2,5-diimines and cis-dichlorobis(isonitrile)platinum(II): Synthesis, cytotoxicity, and catalytic activity in hydrosilylation reactions
Afanasenko, Anastasiia M.; Chulkova, Tatiana G.; Boyarskaya, Irina A.; Islamova, Regina M.; Legin, Anton A.; Keppler, Bernhard K.; Selivanov, Stanislav I.; Vereshchagin, Anatoly N.; Elinson, Michail N.; Haukka, Matti (Elsevier BV, 2020)The reaction of 3,4-diaryl-1H-pyrrol-2,5-diimines with cis-dichlorobis(isonitrile)platinum(II) affords the C,N-chelated diaminocarbene platinum(II) complexes, which have been fully characterized including molecular ... -
Non-conventional synthesis and photophysical studies of platinum(II) complexes with methylene bridged 2,2′-dipyridylamine derivatives
Bulatov, Evgeny; Haukka, Matti (Royal Society of Chemistry, 2019)Methylene bridged 2,2′-dipyridylamine (dpa) derivatives and their metal complexes possess outstanding properties due to their inherent structural flexibility. Synthesis of such complexes typically involves derivatization ...