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An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide

Abstract
The oxidation of (oxime)PtII species using the electrophilic chlorine-based oxidant N,N-dichlorotosylamide (4-CH3C6H4SO2NCl2) was studied. The reactions of trans-[PtCl2(oxime)2] (where oxime = acetoxime, cyclopentanone oxime, or acetaldoxime) with this oxidant led to trans-[PtCl4(oxime)2] products. The oxidation of trans-[Pt(o-OC6H4CH = NOH)2] at room temperature gave trans-[PtCl2(o-OC6H4CH = NOH)2], whereas the same reaction upon heating was accompanied by electrophilic substitution of the benzene rings.
Main Authors
Afanasenko, Anastasiia M. Bulatov, Evgeny Chulkova, Tatiana G. Haukka, Matti Dolgushin, Fedor M.
Format
Articles Research article
Published
2016
Series
Transition Metal Chemistry
Subjects
platinum complexes
oxidation
oxidative chlorination
oxime ligands
Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/25598941
Publisher
Springer International Publishing
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-202011046518Use this for linking
Review status
Peer reviewed
ISSN
0340-4285
DOI
https://doi.org/10.1007/s11243-016-0034-7
Language
English
Published in
Transition Metal Chemistry
Citation
  • Afanasenko, A. M., Bulatov, E., Chulkova, T. G., Haukka, M., & Dolgushin, F. M. (2016). An efficient method for selective oxidation of (oxime)Pt(II) to (oxime)Pt(IV) species using N,N-dichlorotosylamide. Transition Metal Chemistry, 41(4), 387-392. https://doi.org/10.1007/s11243-016-0034-7
License
In CopyrightOpen Access
Copyright© 2016, Springer International Publishing Switzerland

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