dc.contributor.author | Puerta Lombardi, Braulio Michele | |
dc.contributor.author | Gendy, Chris | |
dc.contributor.author | Gelfand, Benjamin S. | |
dc.contributor.author | Bernard, Guy M. | |
dc.contributor.author | Wasylishen, Roderick E. | |
dc.contributor.author | Tuononen, Heikki M. | |
dc.contributor.author | Roesler, Roland | |
dc.date.accessioned | 2020-10-30T10:15:46Z | |
dc.date.available | 2020-10-30T10:15:46Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Puerta Lombardi, B. M., Gendy, C., Gelfand, B. S., Bernard, G. M., Wasylishen, R. E., Tuononen, H. M., & Roesler, R. (2021). Side‐on Coordination in Isostructural Nitrous Oxide and Carbon Dioxide Complexes of Nickel. <i>Angewandte Chemie</i>, <i>60</i>(13), 7077-7081. <a href="https://doi.org/10.1002/anie.202011301" target="_blank">https://doi.org/10.1002/anie.202011301</a> | |
dc.identifier.other | CONVID_43409514 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/72406 | |
dc.description.abstract | A nickel complex incorporating an N2O ligand with a rare η2‐N,N’‐coordination mode was isolated and characterized by X‐ray crystallography, as well as by IR and solid‐state NMR augmented by 15N‐labeling experiments. The isoelectronic nickel CO2 complex reported for comparison features a very similar solid‐state structure. Computational studies revealed that η2‐N2O binds to nickel slightly stronger than η2‐CO2 in this case, and comparably to or slightly stronger than η2‐CO2 to transition metals in general. Comparable transition state energies for the formation of isomeric η2‐N,N’‐ and η2‐N,O‐complexes, and a negligible activation barrier for the decomposition of the latter likely account for the limited stability of the N2O complex. | en |
dc.format.mimetype | application/pdf | |
dc.language | eng | |
dc.language.iso | eng | |
dc.publisher | Wiley-VCH Verlag | |
dc.relation.ispartofseries | Angewandte Chemie | |
dc.rights | CC BY 4.0 | |
dc.subject.other | nickel | |
dc.subject.other | nitrous oxide | |
dc.subject.other | carbon dioxide | |
dc.subject.other | N-heterocyclic carbene | |
dc.subject.other | back bonding | |
dc.title | Side‐on Coordination in Isostructural Nitrous Oxide and Carbon Dioxide Complexes of Nickel | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202010306451 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Epäorgaaninen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Inorganic Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 7077-7081 | |
dc.relation.issn | 1433-7851 | |
dc.relation.numberinseries | 13 | |
dc.relation.volume | 60 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2020 the Authors | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 772510 | |
dc.relation.grantnumber | 772510 | |
dc.relation.projectid | info:eu-repo/grantAgreement/EC/H2020/772510/EU//SMAC-MC | |
dc.subject.yso | typpioksidi | |
dc.subject.yso | kompleksiyhdisteet | |
dc.subject.yso | nikkeli | |
dc.subject.yso | hiilidioksidi | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p21478 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p19926 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p4728 | |
dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
dc.relation.doi | 10.1002/anie.202011301 | |
dc.relation.funder | European Commission | en |
dc.relation.funder | Euroopan komissio | fi |
jyx.fundingprogram | ERC Consolidator Grant | en |
jyx.fundingprogram | ERC Consolidator Grant | fi |
jyx.fundinginformation | Financial support was provided by the Universities of Calgary, Jyväskylä, and Alberta, as well as the NSERC of Canada in the form of Discovery Grants #2019-07195 to R.R. and #2019-06816 to R.E.W. The project received funding from the European Research Council under the EU's Horizon 2020 programme (grant #772510 to H.M.T). R.E.W acknowledges the CFI and the Government of Alberta for NMR Facilities support. Computational resources were provided by the Finnish Grid and Cloud Infra-structure (persistent identifier urn:nbn:fi:research-infras-2016072533) and the University of Calgary. | |
dc.type.okm | A1 | |