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dc.contributor.authorPuerta Lombardi, Braulio Michele
dc.contributor.authorGendy, Chris
dc.contributor.authorGelfand, Benjamin S.
dc.contributor.authorBernard, Guy M.
dc.contributor.authorWasylishen, Roderick E.
dc.contributor.authorTuononen, Heikki M.
dc.contributor.authorRoesler, Roland
dc.date.accessioned2020-10-30T10:15:46Z
dc.date.available2020-10-30T10:15:46Z
dc.date.issued2021
dc.identifier.citationPuerta Lombardi, B. M., Gendy, C., Gelfand, B. S., Bernard, G. M., Wasylishen, R. E., Tuononen, H. M., & Roesler, R. (2021). Side‐on Coordination in Isostructural Nitrous Oxide and Carbon Dioxide Complexes of Nickel. <i>Angewandte Chemie</i>, <i>60</i>(13), 7077-7081. <a href="https://doi.org/10.1002/anie.202011301" target="_blank">https://doi.org/10.1002/anie.202011301</a>
dc.identifier.otherCONVID_43409514
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/72406
dc.description.abstractA nickel complex incorporating an N2O ligand with a rare η2‐N,N’‐coordination mode was isolated and characterized by X‐ray crystallography, as well as by IR and solid‐state NMR augmented by 15N‐labeling experiments. The isoelectronic nickel CO2 complex reported for comparison features a very similar solid‐state structure. Computational studies revealed that η2‐N2O binds to nickel slightly stronger than η2‐CO2 in this case, and comparably to or slightly stronger than η2‐CO2 to transition metals in general. Comparable transition state energies for the formation of isomeric η2‐N,N’‐ and η2‐N,O‐complexes, and a negligible activation barrier for the decomposition of the latter likely account for the limited stability of the N2O complex.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsCC BY 4.0
dc.subject.othernickel
dc.subject.othernitrous oxide
dc.subject.othercarbon dioxide
dc.subject.otherN-heterocyclic carbene
dc.subject.otherback bonding
dc.titleSide‐on Coordination in Isostructural Nitrous Oxide and Carbon Dioxide Complexes of Nickel
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202010306451
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineEpäorgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centeren
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineInorganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange7077-7081
dc.relation.issn1433-7851
dc.relation.numberinseries13
dc.relation.volume60
dc.type.versionacceptedVersion
dc.rights.copyright© 2020 the Authors
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber772510
dc.relation.grantnumber772510
dc.relation.projectidinfo:eu-repo/grantAgreement/EC/H2020/772510/EU//SMAC-MC
dc.subject.ysotyppioksidi
dc.subject.ysokompleksiyhdisteet
dc.subject.ysonikkeli
dc.subject.ysohiilidioksidi
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p21478
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p19926
jyx.subject.urihttp://www.yso.fi/onto/yso/p4728
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1002/anie.202011301
dc.relation.funderEuroopan komissiofi
dc.relation.funderEuropean Commissionen
jyx.fundingprogramERC Consolidator Grantfi
jyx.fundingprogramERC Consolidator Granten
jyx.fundinginformationFinancial support was provided by the Universities of Calgary, Jyväskylä, and Alberta, as well as the NSERC of Canada in the form of Discovery Grants #2019-07195 to R.R. and #2019-06816 to R.E.W. The project received funding from the European Research Council under the EU's Horizon 2020 programme (grant #772510 to H.M.T). R.E.W acknowledges the CFI and the Government of Alberta for NMR Facilities support. Computational resources were provided by the Finnish Grid and Cloud Infra-structure (persistent identifier urn:nbn:fi:research-infras-2016072533) and the University of Calgary.


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