A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air
| dc.contributor.author | Kundu, Gourab | |
| dc.contributor.author | Sperger, Theresa | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Schoenebeck, Franziska | |
| dc.date.accessioned | 2020-10-19T08:55:53Z | |
| dc.date.available | 2020-10-19T08:55:53Z | |
| dc.date.issued | 2020 | |
| dc.identifier.citation | Kundu, G., Sperger, T., Rissanen, K., & Schoenebeck, F. (2020). A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air. <i>Angewandte Chemie</i>, <i>59</i>(49), 21930-21934. <a href="https://doi.org/10.1002/anie.202009115" target="_blank">https://doi.org/10.1002/anie.202009115</a> | |
| dc.identifier.other | CONVID_42871813 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/72239 | |
| dc.description.abstract | We report a new air‐stable PdI dimer, [Pd(μ‐I)(PCy2tBu)]2, which triggers E‐selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C−C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C−Br, C−OTf/OFs, and C−Cl bonds in poly(pseudo)halogenated arenes, displaying superior activity over previous PdI dimer generations for substrates that bear substituents ortho to C−OTf. | en |
| dc.format.mimetype | application/pdf | |
| dc.language | eng | |
| dc.language.iso | eng | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.relation.ispartofseries | Angewandte Chemie | |
| dc.rights | CC BY 4.0 | |
| dc.subject.other | homogeneous catalysis | |
| dc.subject.other | C−C coupling | |
| dc.subject.other | chemoselectivity | |
| dc.subject.other | olefin | |
| dc.subject.other | migration | |
| dc.subject.other | palladium | |
| dc.title | A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202010196298 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Orgaaninen kemia | fi |
| dc.contributor.oppiaine | Organic Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 21930-21934 | |
| dc.relation.issn | 1433-7851 | |
| dc.relation.numberinseries | 49 | |
| dc.relation.volume | 59 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © 2020 the Authors | |
| dc.rights.accesslevel | openAccess | fi |
| dc.subject.yso | palladium | |
| dc.subject.yso | katalyysi | |
| dc.subject.yso | katalyytit | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p26929 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p8704 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p15480 | |
| dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
| dc.relation.doi | 10.1002/anie.202009115 | |
| jyx.fundinginformation | We thank the European Research Council (ERC‐864849) for funding. Open access funding was enabled and organized by Projekt DEAL. | |
| dc.type.okm | A1 |
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