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dc.contributor.authorKundu, Gourab
dc.contributor.authorSperger, Theresa
dc.contributor.authorRissanen, Kari
dc.contributor.authorSchoenebeck, Franziska
dc.date.accessioned2020-10-19T08:55:53Z
dc.date.available2020-10-19T08:55:53Z
dc.date.issued2020
dc.identifier.citationKundu, G., Sperger, T., Rissanen, K., & Schoenebeck, F. (2020). A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air. <i>Angewandte Chemie</i>, <i>59</i>(49), 21930-21934. <a href="https://doi.org/10.1002/anie.202009115" target="_blank">https://doi.org/10.1002/anie.202009115</a>
dc.identifier.otherCONVID_42871813
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/72239
dc.description.abstractWe report a new air‐stable PdI dimer, [Pd(μ‐I)(PCy2tBu)]2, which triggers E‐selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C−C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C−Br, C−OTf/OFs, and C−Cl bonds in poly(pseudo)halogenated arenes, displaying superior activity over previous PdI dimer generations for substrates that bear substituents ortho to C−OTf.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsCC BY 4.0
dc.subject.otherhomogeneous catalysis
dc.subject.otherC−C coupling
dc.subject.otherchemoselectivity
dc.subject.otherolefin
dc.subject.othermigration
dc.subject.otherpalladium
dc.titleA Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202010196298
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange21930-21934
dc.relation.issn1433-7851
dc.relation.numberinseries49
dc.relation.volume59
dc.type.versionpublishedVersion
dc.rights.copyright© 2020 the Authors
dc.rights.accesslevelopenAccessfi
dc.subject.ysopalladium
dc.subject.ysokatalyysi
dc.subject.ysokatalyytit
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p26929
jyx.subject.urihttp://www.yso.fi/onto/yso/p8704
jyx.subject.urihttp://www.yso.fi/onto/yso/p15480
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1002/anie.202009115
jyx.fundinginformationWe thank the European Research Council (ERC‐864849) for funding. Open access funding was enabled and organized by Projekt DEAL.


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