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dc.contributor.authorPan, Fangfang
dc.contributor.authorBeyeh, Ngong Kodiah
dc.contributor.authorRissanen, Kari
dc.date.accessioned2020-07-10T06:02:13Z
dc.date.available2020-07-10T06:02:13Z
dc.date.issued2015
dc.identifier.citationPan, F., Beyeh, N. K., & Rissanen, K. (2015). Concerted Halogen-Bonded Networks with N-Alkyl Ammonium Resorcinarene Bromides: From Dimeric Dumbbell to Capsular Architectures. <i>Journal of the American Chemical Society</i>, <i>137</i>(32), 10406-10413. <a href="https://doi.org/10.1021/jacs.5b06590" target="_blank">https://doi.org/10.1021/jacs.5b06590</a>
dc.identifier.otherCONVID_24851882
dc.identifier.otherTUTKAID_66940
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/71115
dc.description.abstractN-Alkyl ammonium resorcinarene bromides and 1,4-diiodooctafluorobutane via multiple intermolecular halogen bonds (XB) form different exotic supramolecular architectures through subtle changes of the upper rim substituents. Dimeric dumbbell-like assembly with encapsulated guest molecules is generated with N-benzyl substituents. The N-hexyl groups engender an XB-induced polymeric pseudocapsule and an XB-induced dimeric capsule with entrapped 1,4-dioxane guest molecules. The N-propyl and N-cyclohexyl groups generate deep cavity cavitands. The deep cavity cavitands possess cavities for self-inclusion leading to polymeric herringbone arrangement in one direction and that pack into 3D polymeric arrangement resembling egg crate-like supramolecular networks. These assemblies are studied in solution via NMR spectroscopy and in the solid state via X-ray crystallography.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesJournal of the American Chemical Society
dc.rightsCC BY 4.0
dc.subject.otherhalogen bonding
dc.titleConcerted Halogen-Bonded Networks with N-Alkyl Ammonium Resorcinarene Bromides: From Dimeric Dumbbell to Capsular Architectures
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202006234363
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2020-06-23T09:15:08Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange10406-10413
dc.relation.issn0002-7863
dc.relation.numberinseries32
dc.relation.volume137
dc.type.versionpublishedVersion
dc.rights.copyright© 2015 American Chemical Society
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber263256
dc.subject.ysosupramolekulaarinen kemia
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p37759
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.1021/jacs.5b06590
dc.relation.funderSuomen Akatemiafi
dc.relation.funderResearch Council of Finlanden
jyx.fundingprogramAkatemiaprofessorin tehtävä, SAfi
jyx.fundingprogramResearch post as Academy Professor, AoFen
jyx.fundinginformationN.K.B., F.P., and K.R. gratefully acknowledge the Academy of Finland (N.K.B.: grant no. 258653, K.R.,: grant nos. 263256 and 265328) and the University of Jyvaskyla for financial support.
dc.type.okmA1


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