Binding Behavior of Carbonmonoxide to Gold Atoms on Ag(001)
| dc.contributor.author | Kuhness, David | |
| dc.contributor.author | Pal, Jagriti | |
| dc.contributor.author | Yang, Hyun Jin | |
| dc.contributor.author | Mammen, Nisha | |
| dc.contributor.author | Honkala, Karoliina | |
| dc.contributor.author | Häkkinen, Hannu | |
| dc.contributor.author | Schneider, Wolf-Dieter | |
| dc.contributor.author | Heyde, Markus | |
| dc.contributor.author | Freund, Hans-Joachim | |
| dc.date.accessioned | 2020-07-01T10:14:04Z | |
| dc.date.available | 2020-07-01T10:14:04Z | |
| dc.date.issued | 2020 | |
| dc.identifier.citation | Kuhness, D., Pal, J., Yang, H. J., Mammen, N., Honkala, K., Häkkinen, H., Schneider, W.-D., Heyde, M., & Freund, H.-J. (2020). Binding Behavior of Carbonmonoxide to Gold Atoms on Ag(001). <i>Topics in Catalysis</i>, <i>63</i>(15-18), 1578-1584. <a href="https://doi.org/10.1007/s11244-020-01290-3" target="_blank">https://doi.org/10.1007/s11244-020-01290-3</a> | |
| dc.identifier.other | CONVID_36022740 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/71009 | |
| dc.description.abstract | The adsorption behavior of single CO molecules at 4 K bound to Au adatoms on a Ag(001) metal surface is studied with scanning tunneling microscopy (STM) and inelastic electron tunneling spectroscopy (IETS). In contrast to earlier observations two different binding configurations are observed—one on top of a Au adatom and the other one adsorbed laterally to Au on Ag(001). Moreover, IETS reveals different low-energy vibrational energies for the two binding sites as compared to the one for a single CO molecule bound to Ag(001). Density functional theory (DFT) calculations of the adsorption energies, the diffusion barriers, and the vibrational frequencies of the CO molecule on the different binding sites rationalize the experimental findings. | en |
| dc.format.mimetype | application/pdf | |
| dc.language | eng | |
| dc.language.iso | eng | |
| dc.publisher | Springer | |
| dc.relation.ispartofseries | Topics in Catalysis | |
| dc.rights | CC BY 4.0 | |
| dc.subject.other | CO | |
| dc.subject.other | Au | |
| dc.subject.other | Ag(001) | |
| dc.subject.other | adsorption | |
| dc.title | Binding Behavior of Carbonmonoxide to Gold Atoms on Ag(001) | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202007015192 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Fysiikan laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.laitos | Department of Physics | en |
| dc.contributor.oppiaine | Fysikaalinen kemia | fi |
| dc.contributor.oppiaine | Physical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 1578-1584 | |
| dc.relation.issn | 1022-5528 | |
| dc.relation.numberinseries | 15-18 | |
| dc.relation.volume | 63 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © The Author(s) 2020 | |
| dc.rights.accesslevel | openAccess | fi |
| dc.relation.grantnumber | 277222 | |
| dc.relation.grantnumber | 319208 | |
| dc.subject.yso | kulta | |
| dc.subject.yso | adsorptio | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p19016 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p13395 | |
| dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
| dc.relation.doi | 10.1007/s11244-020-01290-3 | |
| dc.relation.funder | Research Council of Finland | en |
| dc.relation.funder | Research Council of Finland | en |
| dc.relation.funder | Suomen Akatemia | fi |
| dc.relation.funder | Suomen Akatemia | fi |
| jyx.fundingprogram | Academy Project, AoF | en |
| jyx.fundingprogram | Research costs of Academy Professor, AoF | en |
| jyx.fundingprogram | Akatemiahanke, SA | fi |
| jyx.fundingprogram | Akatemiaprofessorin tutkimuskulut, SA | fi |
| jyx.fundinginformation | Open access funding provided by Projekt DEAL. The theoretical work was supported by the Academy of Finland through Projects 319208 (H.H.) and 277222 (K.H.). Computations were made at the Barcelona Supercomputing Center as part of a PRACE Project 2018194723 and at the JYU Node of the FGCI Infrastructure (Persistent Identifier urn:nbn:fi:research-infras-2016072533). | |
| dc.type.okm | A1 |
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