Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds : the distinct distance tuning of C-C and its antipodal B-B
Abstract
Four-fold aryl substituted o-carborane derivatives with defined patterns of substitution at the antipodal region of the cluster carbon atoms have been achieved. It is proven that this region is congested but lacks steric hindrance. Also, the two antipodal sites Cc-Cc and B9-B12 are affected very distinctly by electron donor substituents.
Main Authors
Format
Articles
Research article
Published
2019
Series
Subjects
Publication in research information system
Publisher
Royal Society of Chemistry
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201910114394Käytä tätä linkitykseen.
Review status
Peer reviewed
ISSN
1359-7345
DOI
https://doi.org/10.1039/C9CC04526K
Language
English
Published in
Chemical Communications
Citation
- Kelemen, Z., Pepiol, A., Lupu, M., Sillanpää, R., Hänninen, M. M., Teixidor, F., & Viñas, C. (2019). Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds : the distinct distance tuning of C-C and its antipodal B-B. Chemical Communications, 55(61), 8927-8930. https://doi.org/10.1039/C9CC04526K
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Additional information about funding
This work has been supported by the Spanish Ministerio de Economía y Competitividad (CTQ2016-75150-R), the Generalitat de Catalunya (2017SGR1720) and European Union's Horizon 2020 Marie Skłodowska-Curie grant agreement MSCA-IF-2016-751587.
Copyright© The Royal Society of Chemistry 2019