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dc.contributor.authorGálico, Diogo A.
dc.contributor.authorMarin, Riccardo
dc.contributor.authorBrunet, Gabriel
dc.contributor.authorErrulat, Dylan
dc.contributor.authorHemmer, Eva
dc.contributor.authorSigoli, Fernando A.
dc.contributor.authorMoilanen, Jani
dc.contributor.authorMurugesu, Muralee
dc.date.accessioned2019-08-30T06:34:30Z
dc.date.available2019-08-30T06:34:30Z
dc.date.issued2019
dc.identifier.citationGálico, D. A., Marin, R., Brunet, G., Errulat, D., Hemmer, E., Sigoli, F. A., Moilanen, J., & Murugesu, M. (2019). Triplet-State Position and Crystal-Field Tuning in Opto‐Magnetic Lanthanide Complexes : Two Sides of the Same Coin. <i>Chemistry : A European Journal</i>, <i>25</i>(64), 14625-14637. <a href="https://doi.org/10.1002/chem.201902837" target="_blank">https://doi.org/10.1002/chem.201902837</a>
dc.identifier.otherCONVID_32521308
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/65374
dc.description.abstractLanthanide complex‐based luminescence thermometry and single‐molecule magnetism are two effervescent research fields, owing to the great promise they hold from an application standpoint. The high thermal sensitivity achievable, their contactless nature, along with sub‐micrometric spatial resolution make these luminescent thermometers appealing for accurate temperature probing in miniaturized electronics. To that end, single‐molecule magnets (SMMs) are expected to revolutionize the field of spintronics, thanks to the improvements made in terms of their working temperature – now surpassing that of liquid nitrogen – and manipulation of their spin state. Hence, the combination of such opto‐magnetic properties in a single molecule is desirable in the aim of overcoming, among others, addressability issues. Yet, improvements have to be made through design strategies for the realization of the aforementioned goal. Moving forward from these considerations, we present a thorough investigation of the effect that changes in the ligand scaffold of a family of terbium complexes have on their performance as luminescent thermometers and SMMs. In particular, an increased number of electron withdrawing groups yields modifications of the metal coordination environment and a lowering of the triplet state of the ligands. These effects are tightly intertwined, thus, resulting in concomitant variations of the SMM and the luminescence thermometry behaviour of the complexes.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesChemistry : A European Journal
dc.rightsIn Copyright
dc.subject.othersingle-molecule magnets
dc.subject.otherluminescence
dc.subject.otherthermometry
dc.subject.othermolecular structures
dc.subject.otherlanthanides
dc.titleTriplet-State Position and Crystal-Field Tuning in Opto‐Magnetic Lanthanide Complexes : Two Sides of the Same Coin
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201908303978
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange14625-14637
dc.relation.issn0947-6539
dc.relation.numberinseries64
dc.relation.volume25
dc.type.versionacceptedVersion
dc.rights.copyright© 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber315829
dc.relation.grantnumber320015
dc.subject.ysoluminesenssi
dc.subject.ysokompleksiyhdisteet
dc.subject.ysomagneettiset ominaisuudet
dc.subject.ysoharvinaiset maametallit
dc.subject.ysolämpömittarit
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p1646
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p597
jyx.subject.urihttp://www.yso.fi/onto/yso/p15798
jyx.subject.urihttp://www.yso.fi/onto/yso/p1470
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/chem.201902837
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderResearch Council of Finlanden
dc.relation.funderResearch Council of Finlanden
jyx.fundingprogramAkatemiatutkija, SAfi
jyx.fundingprogramAkatemiatutkijan tutkimuskulut, SAfi
jyx.fundingprogramAcademy Research Fellow, AoFen
jyx.fundingprogramResearch costs of Academy Research Fellow, AoFen
jyx.fundinginformationM.M.and E.H.thank the University of Ottawa, the CFI and NSERC for their financial support. F.A.S. and D.A.G. are indebted to CNPq, CAPES and FAPESP (grant: 2013/22127-2) and INOMAT (FAPESP grant: 2014/50906-9), for financial support. Authors would like to thank the Multiuser Laboratory of Advanced Optical Spectroscopy –Institute of Chemistry –UNICAMP. J.O.M. acknowledges the Academy of Finland for the funding (315829, 320015) as well as Prof. H. M. Tuononen, University of Jyväskylä, Jyväskylä, Finland for providing computational resources.
dc.type.okmA1


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