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dc.contributor.authorDing, Xin
dc.contributor.authorTuikka, Matti
dc.contributor.authorRissanen, Kari
dc.contributor.authorHaukka, Matti
dc.date.accessioned2019-07-02T10:46:44Z
dc.date.available2019-07-02T10:46:44Z
dc.date.issued2019
dc.identifier.citationDing, X., Tuikka, M., Rissanen, K., & Haukka, M. (2019). Extended Assemblies of Ru(bpy)(CO)2X2 (X = Cl, Br, I) Molecules Linked by 1,4-Diiodotetrafluoro-Benzene (DITFB) Halogen Bond Donors. <i>Crystals</i>, <i>9</i>(6), Article 319. <a href="https://doi.org/10.3390/cryst9060319" target="_blank">https://doi.org/10.3390/cryst9060319</a>
dc.identifier.otherCONVID_31253024
dc.identifier.otherTUTKAID_81819
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/64964
dc.description.abstractThe ruthenium carbonyl compounds, Ru(bpy)(CO)2X2 (X = Cl, Br or I) act as neutral halogen bond (XB) acceptors when co-crystallized with 1,4-diiodotetrafluoro-benzene (DITFB). The halogen bonding strength of the Ru-X···I halogen bonds follow the nucleophilic character of the halido ligand. The strongest halogen bond occurs between the chlorido ligand and the iodide atoms of the DITFB. All three halogen bonded complexes form polymeric assemblies in the solid state. In Ru(bpy)(CO)2Cl2·DITFB (1) and in Ru(bpy)(CO)2Br2·DITFB (2) both halido ligands are halogen bonded to only one DITFB donor. In Ru(bpy)(CO)2I2·DITFB (3) only one of the halido ligands is involved in halogen bonding acting as ditopic center for two DITFB donors. The polymeric structures of 1 and 2 are isomorphic wave-like single chain systems, while the iodine complexes form pairs of linear chains attached together with weak F···O≡C interactions between the closest neighbors. The stronger polarization of the iodide ligand compared to the Cl or Br ligands favors nearly linear C-I···I angles between the XB donor and the metal complex supporting the linear arrangement of the halogen bonded chain.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherMDPI AG
dc.relation.ispartofseriesCrystals
dc.rightsCC BY 4.0
dc.subject.otherhalogen bond
dc.subject.otherruthenium
dc.subject.othercrystal structure
dc.subject.otherbipyridine
dc.subject.othercarbonyl
dc.titleExtended Assemblies of Ru(bpy)(CO)2X2 (X = Cl, Br, I) Molecules Linked by 1,4-Diiodotetrafluoro-Benzene (DITFB) Halogen Bond Donors
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201907023540
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineOrganic Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2019-07-02T09:15:07Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.relation.issn2073-4352
dc.relation.numberinseries6
dc.relation.volume9
dc.type.versionpublishedVersion
dc.rights.copyright© 2019 by the authors.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber295581
dc.subject.ysoorganometalliyhdisteet
dc.subject.ysokiteet
dc.subject.ysokemialliset sidokset
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p28123
jyx.subject.urihttp://www.yso.fi/onto/yso/p15440
jyx.subject.urihttp://www.yso.fi/onto/yso/p10130
dc.rights.urlhttps://creativecommons.org/licenses/by/4.0/
dc.relation.doi10.3390/cryst9060319
dc.relation.funderSuomen Akatemiafi
dc.relation.funderResearch Council of Finlanden
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAcademy Project, AoFen
dc.type.okmA1


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