Fast pyrolysis of hot-water-extracted and delignified Norway spruce (Picea abies) sawdust by Py-GC/MS

Abstract

The thermochemical behavior of Norway spruce (Picea abies) sawdust as such and after various chemical treatments (hot-water extraction, delignification, and hot-water extraction followed by delignification) was investigated by analytical pyrolysis–gas chromatography–mass spectrometry. In each case, the yields of major GC-amenable condensable products were semi-quantitatively measured, and the individual compounds were classified into several compound groups. The formation of these groups from feedstock samples with varying mass portions of their structural constituents (carbohydrates and lignin) was determined at 500 °C and 700 °C with a residence time of 5 s and 20 s. The formation of pyrolysis products was shown to be characteristically dependent on feedstock composition as well as on pyrolysis conditions. This kind of approach was of practical importance with respect to efforts not only to develop rapid characterization tools for lignocellulosics, but also to uncover new biorefinery possibilities to produce bio-oils, for example, enriched either with aliphatic or aromatic constituents.