Show simple item record

dc.contributor.authorKilpatrick, Alexander F. R.
dc.contributor.authorGuo, Fu-Sheng
dc.contributor.authorDay, Benjamin M.
dc.contributor.authorMansikkamäki, Akseli
dc.contributor.authorLayfield, Richard A.
dc.contributor.authorCloke, F. Geoffrey N.
dc.date.accessioned2018-11-23T07:09:36Z
dc.date.available2019-05-30T21:35:30Z
dc.date.issued2018
dc.identifier.citationKilpatrick, A. F. R., Guo, F.-S., Day, B. M., Mansikkamäki, A., Layfield, R. A., & Cloke, F. G. N. (2018). Single-molecule magnet properties of a monometallic dysprosium pentalene complex. <i>Chemical Communications</i>, <i>54</i>(51), 7085-7088. <a href="https://doi.org/10.1039/C8CC03516D" target="_blank">https://doi.org/10.1039/C8CC03516D</a>
dc.identifier.otherCONVID_28105937
dc.identifier.otherTUTKAID_77930
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/60298
dc.description.abstractThe pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2−) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm−1. Whilst the [Cp*]− ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2− ligand.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesChemical Communications
dc.rightsIn Copyright
dc.subject.otherkompleksiyhdisteetfi
dc.subject.othermagneettiset ominaisuudetfi
dc.subject.othercoordination complexesfi
dc.subject.othermagnetic propertiesfi
dc.titleSingle-molecule magnet properties of a monometallic dysprosium pentalene complex
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201811224827
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-11-22T10:15:07Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange7085-7088
dc.relation.issn1359-7345
dc.relation.numberinseries51
dc.relation.volume54
dc.type.versionacceptedVersion
dc.rights.copyright© The Royal Society of Chemistry 2018.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber289172
dc.relation.grantnumber282499
dc.subject.ysokompleksiyhdisteet
dc.subject.ysomagneettiset ominaisuudet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p597
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1039/C8CC03516D
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderResearch Council of Finlanden
dc.relation.funderResearch Council of Finlanden
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAcademy Project, AoFen
jyx.fundingprogramAcademy Project, AoFen
jyx.fundinginformationThe authors thank the European Research Council (AdG grant 247390, CoG grant 646740), the EPSRC (EP/M023885/1, EP/M022064/1), the Academy of Finland (projects 282499, 289172), Prof. H. M. Tuononen (University of Jyväskylä) for providing computational resources, and Dr T. Pugh, Prof. R. N. Nair and Dr A. Achari (Manchester) for assistance with magnetic susceptibility measurements.
dc.type.okmA1


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record

In Copyright
Except where otherwise noted, this item's license is described as In Copyright