Single-molecule magnet properties of a monometallic dysprosium pentalene complex
| dc.contributor.author | Kilpatrick, Alexander F. R. | |
| dc.contributor.author | Guo, Fu-Sheng | |
| dc.contributor.author | Day, Benjamin M. | |
| dc.contributor.author | Mansikkamäki, Akseli | |
| dc.contributor.author | Layfield, Richard A. | |
| dc.contributor.author | Cloke, F. Geoffrey N. | |
| dc.date.accessioned | 2018-11-23T07:09:36Z | |
| dc.date.available | 2019-05-30T21:35:30Z | |
| dc.date.issued | 2018 | |
| dc.identifier.citation | Kilpatrick, A. F. R., Guo, F.-S., Day, B. M., Mansikkamäki, A., Layfield, R. A., & Cloke, F. G. N. (2018). Single-molecule magnet properties of a monometallic dysprosium pentalene complex. <i>Chemical Communications</i>, <i>54</i>(51), 7085-7088. <a href="https://doi.org/10.1039/C8CC03516D" target="_blank">https://doi.org/10.1039/C8CC03516D</a> | |
| dc.identifier.other | CONVID_28105937 | |
| dc.identifier.other | TUTKAID_77930 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/60298 | |
| dc.description.abstract | The pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2−) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm−1. Whilst the [Cp*]− ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2− ligand. | fi |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | Royal Society of Chemistry | |
| dc.relation.ispartofseries | Chemical Communications | |
| dc.rights | In Copyright | |
| dc.subject.other | kompleksiyhdisteet | fi |
| dc.subject.other | magneettiset ominaisuudet | fi |
| dc.subject.other | coordination complexes | fi |
| dc.subject.other | magnetic properties | fi |
| dc.title | Single-molecule magnet properties of a monometallic dysprosium pentalene complex | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201811224827 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Nanoscience Center | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.contributor.oppiaine | Nanoscience Center | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2018-11-22T10:15:07Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 7085-7088 | |
| dc.relation.issn | 1359-7345 | |
| dc.relation.numberinseries | 51 | |
| dc.relation.volume | 54 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © The Royal Society of Chemistry 2018. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.relation.grantnumber | 289172 | |
| dc.relation.grantnumber | 282499 | |
| dc.subject.yso | kompleksiyhdisteet | |
| dc.subject.yso | magneettiset ominaisuudet | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p597 | |
| dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
| dc.relation.doi | 10.1039/C8CC03516D | |
| dc.relation.funder | Suomen Akatemia | fi |
| dc.relation.funder | Suomen Akatemia | fi |
| dc.relation.funder | Research Council of Finland | en |
| dc.relation.funder | Research Council of Finland | en |
| jyx.fundingprogram | Akatemiahanke, SA | fi |
| jyx.fundingprogram | Akatemiahanke, SA | fi |
| jyx.fundingprogram | Academy Project, AoF | en |
| jyx.fundingprogram | Academy Project, AoF | en |
| jyx.fundinginformation | The authors thank the European Research Council (AdG grant 247390, CoG grant 646740), the EPSRC (EP/M023885/1, EP/M022064/1), the Academy of Finland (projects 282499, 289172), Prof. H. M. Tuononen (University of Jyväskylä) for providing computational resources, and Dr T. Pugh, Prof. R. N. Nair and Dr A. Achari (Manchester) for assistance with magnetic susceptibility measurements. | |
| dc.type.okm | A1 |
Files in this item
This item appears in the following Collection(s)
Except where otherwise noted, this item's license is described as In Copyright