Coherent Light Harvesting through Strong Coupling to Confined Light
Groenhof, G., & Toppari, J. (2018). Coherent Light Harvesting through Strong Coupling to Confined Light. Journal of Physical Chemistry Letters, 9(17), 4848-4851. https://doi.org/10.1021/acs.jpclett.8b02032
Julkaistu sarjassa
Journal of Physical Chemistry LettersPäivämäärä
2018Tekijänoikeudet
© 2018 American Chemical Society
When photoactive molecules interact strongly with confined light modes, new hybrid light-matter states may form: the polaritons. These polaritons are coherent superpositions of excitations of the molecules and of the cavity photon. Recently, polaritons were shown to mediate energy transfer between chromophores at distances beyond the Förster limit. Here we explore the potential of strong coupling for light-harvesting applications by means of atomistic molecular dynamics simulations of mixtures of photoreactive and non-photo-reactive molecules strongly coupled to a single confined light mode. These molecules are spatially separated and present at different concentrations. Our simulations suggest that while the excitation is initially fully delocalized over all molecules and the confined light mode, it very rapidly localizes onto one of the photoreactive molecules, which then undergoes the reaction.
Julkaisija
American Chemical SocietyISSN Hae Julkaisufoorumista
1948-7185Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/28214085
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Suomen AkatemiaRahoitusohjelmat(t)
Akatemiahanke, SALisätietoja rahoituksesta
This work was supported by the Academy of Finland (grants 290677 to G.G. and 289947 to J.J.T.).Lisenssi
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