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dc.contributor.authorBravin, Carlo
dc.contributor.authorBadetti, Elena
dc.contributor.authorPuttreddy, Rakesh
dc.contributor.authorPan, Fangfang
dc.contributor.authorRissanen, Kari
dc.contributor.authorLicini, Giulia
dc.contributor.authorZonta, Cristiano
dc.date.accessioned2018-05-25T10:52:27Z
dc.date.available2018-12-04T22:35:23Z
dc.date.issued2018
dc.identifier.citationBravin, C., Badetti, E., Puttreddy, R., Pan, F., Rissanen, K., Licini, G., & Zonta, C. (2018). Binding Profiles of Self-Assembled Supramolecular Cages from ESI-MS Based Methodology. <i>Chemistry: A European Journal</i>, <i>24</i>(12), 2936-2943. <a href="https://doi.org/10.1002/chem.201704725" target="_blank">https://doi.org/10.1002/chem.201704725</a>
dc.identifier.otherCONVID_27910069
dc.identifier.otherTUTKAID_76856
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/58123
dc.description.abstractConfined molecular environments have peculiar characteristics that make their properties unique in the field of biological and chemical sciences. In recent years, advances in supramolecular capsule and cage synthesis have presented the possibility to interpret the principles behind their self‐assembly and functions, which has led to new molecular systems that display outstanding properties in molecular recognition and catalysis. Herein, we report a rapid method based on ESI‐MS to determine the binding profiles for linear saturated dicarboxylic acids in a series of different cages. The cages were obtained by self‐assembly of modified tris(pyridylmethyl)amine (TPMA) complexes and diamines chosen to explore variations in their size and flexibility. This methodology has provided information on how small changes in the structures of the host and guest can contribute to recognition events. Moreover, it was possible to study molecular systems that contain paramagnetic metals, which are not suitable for classical binding‐constant determination by 1H NMR spectroscopy.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley-VCH.
dc.relation.ispartofseriesChemistry: A European Journal
dc.rightsIn Copyright
dc.subject.othersupramolekulaarinen kemiafi
dc.subject.othersupramolecular chemistryfi
dc.titleBinding Profiles of Self-Assembled Supramolecular Cages from ESI-MS Based Methodology
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201805252758
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-05-25T06:15:11Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange2936-2943
dc.relation.issn0947-6539
dc.relation.numberinseries12
dc.relation.volume24
dc.type.versionacceptedVersion
dc.rights.copyright© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
dc.rights.accesslevelopenAccessfi
dc.subject.ysosupramolekulaarinen kemia
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p37759
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/chem.201704725
dc.type.okmA1


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