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dc.contributor.authorGraham, Cameron M. E.
dc.contributor.authorMillet, Clément R. P.
dc.contributor.authorPrice, Amy N.
dc.contributor.authorValjus, Juuso
dc.contributor.authorCowley, Michael J.
dc.contributor.authorTuononen, Heikki
dc.contributor.authorRagogna, Paul J.
dc.date.accessioned2018-05-25T09:25:03Z
dc.date.available2018-11-11T22:35:24Z
dc.date.issued2018
dc.identifier.citationGraham, C. M. E., Millet, C. R. P., Price, A. N., Valjus, J., Cowley, M. J., Tuononen, H., & Ragogna, P. J. (2018). Preparation and Characterization of P2BCh Ring Systems (Ch=S, Se) and Their Reactivity with N-Heterocyclic Carbenes. <i>Chemistry: A European Journal</i>, <i>24</i>(3), 672-680. <a href="https://doi.org/10.1002/chem.201704337" target="_blank">https://doi.org/10.1002/chem.201704337</a>
dc.identifier.otherCONVID_27890137
dc.identifier.otherTUTKAID_76745
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/58105
dc.description.abstractFour-membered rings with a P2BCh core (Ch = S, Se) have been synthesized via reaction of phosphinidene chalcogenide (Ar*P=Ch) and phosphaborene (Mes*P=BNR2). The mechanistic pathways towards these rings are explained by detailed computational work that confirmed the preference for the formation of P–P, not P–B, bonded systems, which seems counterintuitive given that both phosphorus atoms contain bulky ligands. The reactivity of the newly synthesized heterocycles, as well as that of the known (RPCh)n rings (n = 2, 3), was probed by the addition of Nheterocyclic carbenes, which revealed that all investigated compounds can act as sources of low-coordinate phosphorus species.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherWiley-VCH.
dc.relation.ispartofseriesChemistry: A European Journal
dc.rightsIn Copyright
dc.subject.otherheterocycles
dc.titlePreparation and Characterization of P2BCh Ring Systems (Ch=S, Se) and Their Reactivity with N-Heterocyclic Carbenes
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201805232735
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-05-23T09:15:16Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange672-680
dc.relation.issn0947-6539
dc.relation.numberinseries3
dc.relation.volume24
dc.type.versionacceptedVersion
dc.rights.copyright© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
dc.rights.accesslevelopenAccessfi
dc.subject.ysoepäorgaaniset yhdisteet
dc.subject.ysokemiallinen synteesi
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p11314
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/chem.201704337
dc.type.okmA1


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