Self-Complementary Dimers of Oxalamide-Functionalized Resorcinarene Tetrabenzoxazines
Dzolic, Z., Beyeh, N. K., Cetina, M., Turunen, L., & Rissanen, K. (2018). Self-Complementary Dimers of Oxalamide-Functionalized Resorcinarene Tetrabenzoxazines. Chemistry: An Asian Journal, 13(2), 164-169. https://doi.org/10.1002/asia.201701426
Published in
Chemistry: An Asian JournalDate
2018Copyright
© 2018 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
Self‐complementarity is a useful concept in supramolecular chemistry, molecular biology and polymeric systems. Two resorcinarene tetrabenzoxazines decorated with four oxalamide groups were synthesized and characterized. The oxalamide groups possessed self‐complementary hydrogen bonding sites between the carbonyls and amide groups. The self‐complementary nature of the oxalamide groups resulted in self‐included dimeric assemblies. The hydrogen bonding interactions within the tetrabenzoxazines gave rise to the formation of dimers, which were confirmed by single‐crystal X‐ray diffractions analysis and supported by NMR spectroscopy and mass spectrometry. The self‐included dimers were connected by numerous and strong intermolecular N−H⋅⋅⋅O and C−H⋅⋅⋅O hydrogen bonds supplemented with C−H⋅⋅⋅π interactions, forming one‐dimensional polymers, which were then further linked into three‐dimensional networks.
Publisher
Wiley-VCH VerlagISSN Search the Publication Forum
1861-4728Keywords
Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/27404619
Metadata
Show full item recordCollections
Related funder(s)
Research Council of FinlandFunding program(s)
Research post as Academy Professor, AoF; Research costs of Academy Professor, AoFAdditional information about funding
The authors gratefully acknowledge financial support from the Academy of Finland (KR: grant nos. 265328, 263256 and 292746; NKB: grant no. 258653), University of Zagreb, Croatia, Aalto University, and the University of Jyvaskyla, Finland. This work was supported by the Academy of Finland through its Centres of Excellence Programme (HYBER 2014–2019).Related items
Showing items with similar title or keywords.
-
Solid state conformational behavior and interactions of a series of aromatic oligoamide foldamers
Suhonen, Aku (University of Jyväskylä, 2016)The topic of this thesis is aromatic oligoamide foldamers. The literary review of the thesis discusses the general features of foldamers and their design and then focuses on the specific examples of aromatic oligoamide ... -
Systematic Modulation of the Supramolecular Gelation Properties of Bile Acid Alkyl Amides
Kuosmanen, Riikka; Puttreddy, Rakesh; Rissanen, Kari; Sievänen, Elina (Wiley-VCH, 2018)The self-assembly properties of nine low-molecular-weight gelators (LMWGs) based on bile acid alkyl amides were studied in detail. Based on the results, the number of hydroxyl groups attached to the steroidal backbone plays ... -
Spatial localization of hotspots in Fano-resonant plasmonic oligomers for surface-enhanced coherent anti-Stokes Raman scattering
Dutta, Arpan; Vartiainen, Erik M. (Springer, 2020)Realization of Fano resonance in plasmonic oligomers is often exploited to design efficient plasmonic substrates for surface-enhanced coherent anti-Stokes Raman scattering. Disk-type Fano-resonant plasmonic oligomers are ... -
Trade-offs or Complements? : Balancing Diversified Stakeholder Expectations, Institutional Pressures, and Functional Demands in the Strategic Management of Business Schools
Ojala, Anu (Association of Business Schools Finland, 2019)While scholars and practitioners have warned that business schools are losing their edge in creating and disseminating relevant knowledge in the crosscurrent of environmental demands, the management and organization of ... -
Measurements of binding energies and electromagnetic moments of silver isotopes : A complementary benchmark of density functional theory
de Groote, R. P.; Nesterenko, D. A.; Kankainen, A.; Bissell, M.L.; Beliuskina, O.; Bonnard, J.; Campbell, P.; Canete, L.; Cheal, B.; Delafosse, C.; de Roubin, A.; Devlin, C.S.; Dobaczewski, J.; Eronen, T.; Garcia, Ruiz R. F.; Geldhof, S.; Gins, W.; Hukkanen, M.; Imgram, P.; Mathieson, R.; Koszorús, Á.; Moore, I.D.; Pohjalainen, I.; Reponen, M.; van den Borne, B.; Vilén, M.; Zadvornaya, S. (Elsevier, 2024)We report on a set of high-precision measurements of nuclear binding and excitation energies, as well as nuclear spins, magnetic dipole and electric quadrupole moments of neutron-rich silver isotopes, 113−123Ag. The ...