University of Jyväskylä | JYX Digital Repository

  • English  | Give feedback |
    • suomi
    • English
 
  • Login
JavaScript is disabled for your browser. Some features of this site may not work without it.
View Item 
  • JYX
  • Artikkelit
  • Matemaattis-luonnontieteellinen tiedekunta
  • View Item
JYX > Artikkelit > Matemaattis-luonnontieteellinen tiedekunta > View Item

Self-Complementary Dimers of Oxalamide-Functionalized Resorcinarene Tetrabenzoxazines

ThumbnailFinal Draft
View/Open
1.1 Mb

Downloads:  
Show download detailsHide download details  
Dzolic, Z., Beyeh, N. K., Cetina, M., Turunen, L., & Rissanen, K. (2018). Self-Complementary Dimers of Oxalamide-Functionalized Resorcinarene Tetrabenzoxazines. Chemistry: An Asian Journal, 13(2), 164-169. https://doi.org/10.1002/asia.201701426
Published in
Chemistry: An Asian Journal
Authors
Dzolic, Zoran |
Beyeh, Ngong Kodiah |
Cetina, Mario |
Turunen, Lotta |
Rissanen, Kari
Date
2018
Discipline
Orgaaninen kemiaNanoscience CenterOrganic ChemistryNanoscience Center
Copyright
© 2018 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.

 
Self‐complementarity is a useful concept in supramolecular chemistry, molecular biology and polymeric systems. Two resorcinarene tetrabenzoxazines decorated with four oxalamide groups were synthesized and characterized. The oxalamide groups possessed self‐complementary hydrogen bonding sites between the carbonyls and amide groups. The self‐complementary nature of the oxalamide groups resulted in self‐included dimeric assemblies. The hydrogen bonding interactions within the tetrabenzoxazines gave rise to the formation of dimers, which were confirmed by single‐crystal X‐ray diffractions analysis and supported by NMR spectroscopy and mass spectrometry. The self‐included dimers were connected by numerous and strong intermolecular N−H⋅⋅⋅O and C−H⋅⋅⋅O hydrogen bonds supplemented with C−H⋅⋅⋅π interactions, forming one‐dimensional polymers, which were then further linked into three‐dimensional networks.
Publisher
Wiley-VCH Verlag
ISSN Search the Publication Forum
1861-4728
Keywords
dimers resorcinarenes self-complementarity massaspektrometria karbonyylit obligaatiot vety amidit oligomeeri spektroskopia
DOI
https://doi.org/10.1002/asia.201701426
URI

http://urn.fi/URN:NBN:fi:jyu-201801181265

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/27404619

Metadata
Show full item record
Collections
  • Matemaattis-luonnontieteellinen tiedekunta [4954]
Related funder(s)
Academy of Finland
Funding program(s)
Research post as Academy Professor, AoF; Research costs of Academy Professor, AoF
Additional information about funding
The authors gratefully acknowledge financial support from the Academy of Finland (KR: grant nos. 265328, 263256 and 292746; NKB: grant no. 258653), University of Zagreb, Croatia, Aalto University, and the University of Jyvaskyla, Finland. This work was supported by the Academy of Finland through its Centres of Excellence Programme (HYBER 2014–2019).

Related items

Showing items with similar title or keywords.

  • Solid state conformational behavior and interactions of a series of aromatic oligoamide foldamers 

    Suhonen, Aku (University of Jyväskylä, 2016)
    The topic of this thesis is aromatic oligoamide foldamers. The literary review of the thesis discusses the general features of foldamers and their design and then focuses on the specific examples of aromatic oligoamide ...
  • Systematic Modulation of the Supramolecular Gelation Properties of Bile Acid Alkyl Amides 

    Kuosmanen, Riikka; Puttreddy, Rakesh; Rissanen, Kari; Sievänen, Elina (Wiley-VCH, 2018)
    The self-assembly properties of nine low-molecular-weight gelators (LMWGs) based on bile acid alkyl amides were studied in detail. Based on the results, the number of hydroxyl groups attached to the steroidal backbone plays ...
  • Anion-driven encapsulation of cationic guests inside pyridine[4]arene dimers 

    Kiesilä, Anniina; Moilanen, Jani O.; Kruve, Anneli.; Schalley, Christoph A.; Barran, Perdita; Kalenius, Elina (Beilstein Institut zur Foerderung der Chemischen Wissenschaften, 2019)
    Pyridine[4]arenes have previously been considered as anion binding hosts due to the electron-poor nature of the pyridine ring. Herein, we demonstrate the encapsulation of Me4N+ cations inside a dimeric hydrogen-bonded ...
  • Spatial localization of hotspots in Fano-resonant plasmonic oligomers for surface-enhanced coherent anti-Stokes Raman scattering 

    Dutta, Arpan; Vartiainen, Erik M. (Springer, 2020)
    Realization of Fano resonance in plasmonic oligomers is often exploited to design efficient plasmonic substrates for surface-enhanced coherent anti-Stokes Raman scattering. Disk-type Fano-resonant plasmonic oligomers are ...
  • Trade-offs or Complements? : Balancing Diversified Stakeholder Expectations, Institutional Pressures, and Functional Demands in the Strategic Management of Business Schools 

    Ojala, Anu (Association of Business Schools Finland, 2019)
    While scholars and practitioners have warned that business schools are losing their edge in creating and disseminating relevant knowledge in the crosscurrent of environmental demands, the management and organization of ...
  • Browse materials
  • Browse materials
  • Articles
  • Conferences and seminars
  • Electronic books
  • Historical maps
  • Journals
  • Tunes and musical notes
  • Photographs
  • Presentations and posters
  • Publication series
  • Research reports
  • Research data
  • Study materials
  • Theses

Browse

All of JYXCollection listBy Issue DateAuthorsSubjectsPublished inDepartmentDiscipline

My Account

Login

Statistics

View Usage Statistics
  • How to publish in JYX?
  • Self-archiving
  • Publish Your Thesis Online
  • Publishing Your Dissertation
  • Publication services

Open Science at the JYU
 
Data Protection Description

Accessibility Statement

Unless otherwise specified, publicly available JYX metadata (excluding abstracts) may be freely reused under the CC0 waiver.
Open Science Centre