Selective recognition of aromatic hydrocarbons by endo-functionalized molecular tubes via C/N-H⋅⋅⋅π interactions
Abstract
Molecular recognition of aromatic hydrocarbons by four endo-functionalized molecular tubes has been studied by 1H NMR spectroscopy, computational methods, and single crystal X-ray crystallography. The binding selectivity is rationalized by invoking shape complementarity and dipole alignment. The non-covalent interactions are proved to predominantly be C/N-H⋅⋅⋅π interactions.
Main Authors
Format
Articles
Research article
Published
2018
Series
Subjects
Publication in research information system
Publisher
Elsevier Ltd; Chinese Chemical Society
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201801151206Use this for linking
Review status
Peer reviewed
ISSN
1001-8417
DOI
https://doi.org/10.1016/j.cclet.2017.07.005
Language
English
Published in
Chinese Chemical Letters
Citation
- Huang, G.-B., Liu, W.-E., Valkonen, A., Yao, H., Rissanen, K., & Jiang, W. (2018). Selective recognition of aromatic hydrocarbons by endo-functionalized molecular tubes via C/N-H⋅⋅⋅π interactions. Chinese Chemical Letters, 29(1), 91-94. https://doi.org/10.1016/j.cclet.2017.07.005
License
Funder(s)
Research Council of Finland
Research Council of Finland
Funding program(s)
Akatemiaprofessorin tutkimuskulut, SA
Akatemiaprofessorin tehtävä, SA
Research costs of Academy Professor, AoF
Research post as Academy Professor, AoF
Additional information about funding
This research was financially supported by the National Natural Science Foundation of China (No. 21572097), Thousand Young Talents Program, South University of Science and Technology of China, the Shenzhen special funds for the development of biomedicine, internet, new energy, and new material industries (Nos. JCYJ20160226192118056, JCYJ20170307105848463), the Startup Program of Yulin Normal University (No. G20160002) and the Academy of Finland (Nos. 263256, 265328 and 292746).
Copyright© 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.