Selective recognition of aromatic hydrocarbons by endo-functionalized molecular tubes via C/N-H⋅⋅⋅π interactions
Huang, G.-B., Liu, W.-E., Valkonen, A., Yao, H., Rissanen, K., & Jiang, W. (2018). Selective recognition of aromatic hydrocarbons by endo-functionalized molecular tubes via C/N-H⋅⋅⋅π interactions. Chinese Chemical Letters, 29(1), 91-94. https://doi.org/10.1016/j.cclet.2017.07.005
Published inChinese Chemical Letters
DisciplineOrgaaninen kemiaOrganic Chemistry
© 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.
Molecular recognition of aromatic hydrocarbons by four endo-functionalized molecular tubes has been studied by 1H NMR spectroscopy, computational methods, and single crystal X-ray crystallography. The binding selectivity is rationalized by invoking shape complementarity and dipole alignment. The non-covalent interactions are proved to predominantly be C/N-H⋅⋅⋅π interactions.
PublisherElsevier Ltd; Chinese Chemical Society
ISSN Search the Publication Forum1001-8417
Publication in research information system
MetadataShow full item record
Related funder(s)Academy of Finland
Funding program(s)Research costs of Academy Professor, AoF; Research post as Academy Professor, AoF
Additional information about fundingThis research was financially supported by the National Natural Science Foundation of China (No. 21572097), Thousand Young Talents Program, South University of Science and Technology of China, the Shenzhen special funds for the development of biomedicine, internet, new energy, and new material industries (Nos. JCYJ20160226192118056, JCYJ20170307105848463), the Startup Program of Yulin Normal University (No. G20160002) and the Academy of Finland (Nos. 263256, 265328 and 292746). ...
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