Show simple item record

dc.contributor.authorTurunen, Lotta
dc.contributor.authorPeuronen, Anssi
dc.contributor.authorForsblom, Samu
dc.contributor.authorKalenius, Elina
dc.contributor.authorLahtinen, Manu
dc.contributor.authorRissanen, Kari
dc.date.accessioned2017-09-13T09:00:56Z
dc.date.available2018-07-29T21:35:43Z
dc.date.issued2017
dc.identifier.citationTurunen, L., Peuronen, A., Forsblom, S., Kalenius, E., Lahtinen, M., & Rissanen, K. (2017). Tetrameric and Dimeric [N∙∙∙I+∙∙∙N] Halogen-Bonded Supramolecular Cages. <i>Chemistry: A European Journal</i>, <i>23</i>(48), 11714-11718. <a href="https://doi.org/10.1002/chem.201702655" target="_blank">https://doi.org/10.1002/chem.201702655</a>
dc.identifier.otherCONVID_27080527
dc.identifier.otherTUTKAID_74222
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/55340
dc.description.abstractTripodal N‐donor ligands are used to form halogen‐bonded assemblies via structurally analogous Ag+‐complexes. Selective formation of discrete tetrameric I6L4 and dimeric I3L2 halonium cages, wherein multiple [N⋅⋅⋅I+⋅⋅⋅N] halogen bonds are used in concert, can be achieved by using sterically rigidified cationic tris(1‐methyl‐1‐azonia‐4‐azabicyclo[2.2.2]octane)‐mesitylene ligand, L1(PF6)3, and flexible ligand 1,3,5‐tris(imidazole‐1‐ylmethyl)‐2,4,6‐trimethylbenzene, L2, respectively. The iodonium cages, I6L14(PF6)18 and I3L22(PF6)3, were obtained through the [N⋅⋅⋅Ag+⋅⋅⋅N]→ [N⋅⋅⋅I+⋅⋅⋅N] cation exchange reaction between the corresponding Ag6L14(PF6)18 and Ag3L22(PF6)3 coordination cages, prepared as intermediates, and I2. The synthesized metallo‐ and halonium cages were studied in solution by NMR, in gas phase by ESI‐MS and in the solid‐state by single crystal X‐ray diffraction.en
dc.language.isoeng
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA
dc.relation.ispartofseriesChemistry: A European Journal
dc.subject.otherhalogen bonds
dc.subject.othersupramolecular cages
dc.titleTetrameric and Dimeric [N∙∙∙I+∙∙∙N] Halogen-Bonded Supramolecular Cages
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201709113698
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-09-11T09:15:11Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange11714-11718
dc.relation.issn0947-6539
dc.relation.numberinseries48
dc.relation.volume23
dc.type.versionacceptedVersion
dc.rights.copyright© 2017 Wiley-VCH Verlag GmbH &Co. This is a final draft version of an article whose final and definitive form has been published by Wiley-VCH. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber263256
dc.relation.grantnumber292746
dc.relation.grantnumber277250
dc.relation.grantnumber278743
dc.relation.grantnumber284562
dc.relation.doi10.1002/chem.201702655
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramAkatemiaprofessorin tehtävä, SAfi
jyx.fundingprogramAkatemiaprofessorin tutkimuskulut, SAfi
jyx.fundingprogramAkatemiahanke, SAfi
jyx.fundingprogramAkatemiatutkijan tehtävä, SAfi
jyx.fundingprogramAkatemiatutkijan tutkimuskulut, SAfi
jyx.fundingprogramResearch post as Academy Professor, AoFen
jyx.fundingprogramResearch costs of Academy Professor, AoFen
jyx.fundingprogramAcademy Project, AoFen
jyx.fundingprogramResearch post as Academy Research Fellow, AoFen
jyx.fundingprogramResearch costs of Academy Research Fellow, AoFen
jyx.fundinginformationThe authors kindly acknowledge the Academy of Finland (K.R.: Nos. 263256, 265328, 292746; E.K.: Nos. 284562 and 278743; M.L.: No. 277250).


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record