Crystal structure and Hirshfeld surface analysis of [N(CH3)4][2,2′-Fe(1,7-closo-C2B9H11)2]

Bennour, Ines; Haukka, Matti; Teixidor, Francesc; Viñas, Clara; Kabadou, Ahlem

doi:10.1016/j.jorganchem.2017.05.047

dc.contributor.author	Bennour, Ines
dc.contributor.author	Haukka, Matti
dc.contributor.author	Teixidor, Francesc
dc.contributor.author	Viñas, Clara
dc.contributor.author	Kabadou, Ahlem
dc.date.accessioned	2017-08-14T05:43:41Z
dc.date.available	2019-10-01T21:35:48Z
dc.date.issued	2017
dc.identifier.citation	Bennour, I., Haukka, M., Teixidor, F., Viñas, C., & Kabadou, A. (2017). Crystal structure and Hirshfeld surface analysis of [N(CH3)4][2,2′-Fe(1,7-closo-C2B9H11)2]. <i>Journal of Organometallic Chemistry</i>, <i>846</i>, 74-80. <a href="https://doi.org/10.1016/j.jorganchem.2017.05.047" target="_blank">https://doi.org/10.1016/j.jorganchem.2017.05.047</a>
dc.identifier.other	CONVID_27022299
dc.identifier.other	TUTKAID_73886
dc.identifier.uri	https://jyx.jyu.fi/handle/123456789/55077
dc.description.abstract	This work investigates the meta-ferrabis(dicarbollide) anion that was isolated as salt of tetramethylammonium. The structure of the obtained crystal consisted of discrete [2,2′-Fe(1,7-closo-C2B9H11)2]− anions and disordered [N(CH3)4]+ cations. The anion had a considerable chemical stability ensured by ionic and Van der Waals interactions. Thus, Hirshfeld surfaces and fingerprint plot were used to visualize, explore, and quantify intermolecular interactions in the crystal lattice of the title compound. This investigation proved that close contacts were dominated by H⋯H interactions.
dc.language.iso	eng
dc.publisher	Elsevier Sequoia
dc.relation.ispartofseries	Journal of Organometallic Chemistry
dc.subject.other	structures: crystals
dc.subject.other	meta-carborane
dc.subject.other	metallabis(dicarbollide)
dc.subject.other	Hirshfeld study
dc.subject.other	dihydrogen bonds
dc.title	Crystal structure and Hirshfeld surface analysis of [N(CH3)4][2,2′-Fe(1,7-closo-C2B9H11)2]
dc.type	article
dc.identifier.urn	URN:NBN:fi:jyu-201708103444
dc.contributor.laitos	Kemian laitos	fi
dc.contributor.laitos	Department of Chemistry	en
dc.contributor.oppiaine	Epäorgaaninen ja analyyttinen kemia	fi
dc.contributor.oppiaine	Inorganic and Analytical Chemistry	en
dc.type.uri	http://purl.org/eprint/type/JournalArticle
dc.date.updated	2017-08-10T06:15:07Z
dc.type.coar	http://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatus	peerReviewed
dc.format.pagerange	74-80
dc.relation.issn	0022-328X
dc.relation.numberinseries	0
dc.relation.volume	846
dc.type.version	acceptedVersion
dc.rights.copyright	© 2017 Elsevier B.V. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevel	openAccess	fi
dc.subject.yso	kemia
dc.subject.yso	röntgenkristallografia
dc.subject.yso	röntgentekniikka
jyx.subject.uri	http://www.yso.fi/onto/yso/p1801
jyx.subject.uri	http://www.yso.fi/onto/yso/p29058
jyx.subject.uri	http://www.yso.fi/onto/yso/p12080
dc.relation.doi	10.1016/j.jorganchem.2017.05.047
dc.type.okm	A1

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