dc.contributor.author | Saloranta, Tiina | |
dc.contributor.author | Peuronen, Anssi | |
dc.contributor.author | Dieterich, Johannes M. | |
dc.contributor.author | Ruokolainen, Janne | |
dc.contributor.author | Lahtinen, Manu | |
dc.contributor.author | Leino, Reko | |
dc.date.accessioned | 2017-04-19T07:16:50Z | |
dc.date.available | 2017-04-19T07:16:50Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Saloranta, T., Peuronen, A., Dieterich, J. M., Ruokolainen, J., Lahtinen, M., & Leino, R. (2016). From Mannose to Small Amphiphilic Polyol: Perfect Linearity Leads To Spontaneous Aggregation. <i>Crystal Growth and Design</i>, <i>16</i>(2), 655-661. <a href="https://doi.org/10.1021/acs.cgd.5b01135" target="_blank">https://doi.org/10.1021/acs.cgd.5b01135</a> | |
dc.identifier.other | CONVID_25581674 | |
dc.identifier.other | TUTKAID_69365 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/53620 | |
dc.description.abstract | Terminally unsaturated and diastereochemically pure polyol derived from d-mannose shows spontaneous aggregation behavior in water solution. In order to study and clarify this unforeseen phenomenon, a conformational study based on NMR spectroscopy combined with ab initio structure analysis using the COSMO-solvation model was pursued. The results, together with X-ray diffraction studies, suggest a low energy linear conformation for this particular substrate both in solid states and in solution. For such small-sized acyclic carbohydrate derivatives, the linear conformation appears to be a key prerequisite for the unusual molecular self-assembly reported herein. | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society | |
dc.relation.ispartofseries | Crystal Growth and Design | |
dc.subject.other | d-mannose | |
dc.subject.other | polyols | |
dc.subject.other | spontaneous aggregation | |
dc.title | From Mannose to Small Amphiphilic Polyol: Perfect Linearity Leads To Spontaneous Aggregation | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201704121980 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2017-04-12T12:15:03Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 655-661 | |
dc.relation.issn | 1528-7483 | |
dc.relation.numberinseries | 2 | |
dc.relation.volume | 16 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2015 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by American Chemical Society. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.doi | 10.1021/acs.cgd.5b01135 | |
dc.type.okm | A1 | |