2-Methylresorcinarene : a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion

Puttreddy, Rakesh; Beyeh, Ngong Kodiah; Kalenius, Elina; Ras, Robin H. A.; Rissanen, Kari

doi:10.1039/C6CC03289C

dc.contributor.author	Puttreddy, Rakesh
dc.contributor.author	Beyeh, Ngong Kodiah
dc.contributor.author	Kalenius, Elina
dc.contributor.author	Ras, Robin H. A.
dc.contributor.author	Rissanen, Kari
dc.date.accessioned	2017-04-04T09:11:28Z
dc.date.available	2017-04-04T09:11:28Z
dc.date.issued	2016
dc.identifier.citation	Puttreddy, R., Beyeh, N. K., Kalenius, E., Ras, R. H. A., & Rissanen, K. (2016). 2-Methylresorcinarene : a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion. <i>Chemical Communications</i>, <i>52</i>(52), 8115-8118. <a href="https://doi.org/10.1039/C6CC03289C" target="_blank">https://doi.org/10.1039/C6CC03289C</a>
dc.identifier.other	CONVID_26085312
dc.identifier.other	TUTKAID_70466
dc.identifier.uri	https://jyx.jyu.fi/handle/123456789/53480
dc.description.abstract	Mono- and tetra-deprotonated 2-methylresorcinarene anions (1 and 2) as their trans-1,4-diammoniumcyclohexane (TDAC)2+ inclusion complexes are reported. The mono-anion forms a fully closed dimeric capsule [1·H2O·MeOH]22− with a cavity volume of 165 Å3 and (TDAC)2+ as the guest with an extremely high packing coefficient, PC = 84.2%, while the tetra-anion forms a close-packed structure with two structurally isomeric tetra-anions 2a and 2b with a 50 : 50 ratio in the crystal lattice.
dc.language.iso	eng
dc.publisher	RSC Publications
dc.relation.ispartofseries	Chemical Communications
dc.subject.other	mono-anions
dc.subject.other	tetra-anions
dc.subject.other	X-ray crystal structure
dc.title	2-Methylresorcinarene : a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion
dc.type	article
dc.identifier.urn	URN:NBN:fi:jyu-201703281780
dc.contributor.laitos	Kemian laitos	fi
dc.contributor.laitos	Department of Chemistry	en
dc.contributor.oppiaine	Orgaaninen kemia	fi
dc.contributor.oppiaine	Nanoscience Center	fi
dc.contributor.oppiaine	Organic Chemistry	en
dc.contributor.oppiaine	Nanoscience Center	en
dc.type.uri	http://purl.org/eprint/type/JournalArticle
dc.date.updated	2017-03-28T12:15:15Z
dc.type.coar	http://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatus	peerReviewed
dc.format.pagerange	8115-8118
dc.relation.issn	1359-7345
dc.relation.numberinseries	52
dc.relation.volume	52
dc.type.version	publishedVersion
dc.rights.copyright	© 2016 the Authors. This is an open access article distributed under the terms of the Creative Commons Attribution License.
dc.rights.accesslevel	openAccess	fi
dc.rights.url	http://creativecommons.org/licenses/by/3.0/
dc.relation.doi	10.1039/C6CC03289C
dc.type.okm	A1

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2-Methylresorcinarene : a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion

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Aineisto kuuluu seuraaviin kokoelmiin

Samankaltainen aineisto

Surprising solvent-induced structural rearrangements in large [N⋯I+⋯N] halogen-bonded supramolecular capsules : an ion mobility-mass spectrometry study ﻿

Rank Structured Approximation Method for Quasi-Periodic Elliptic Problems ﻿

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