2-Methylresorcinarene : a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion
Abstract
Mono- and tetra-deprotonated 2-methylresorcinarene anions (1 and 2) as their trans-1,4-diammoniumcyclohexane (TDAC)2+ inclusion complexes are reported. The mono-anion forms a fully closed dimeric capsule [1·H2O·MeOH]22− with a cavity volume of 165 Å3 and (TDAC)2+ as the guest with an extremely high packing coefficient, PC = 84.2%, while the tetra-anion forms a close-packed structure with two structurally isomeric tetra-anions 2a and 2b with a 50 : 50 ratio in the crystal lattice.
Main Authors
Format
Articles
Research article
Published
2016
Series
Subjects
Publication in research information system
Publisher
RSC Publications
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201703281780Use this for linking
Review status
Peer reviewed
ISSN
1359-7345
DOI
https://doi.org/10.1039/C6CC03289C
Language
English
Published in
Chemical Communications
Citation
- Puttreddy, R., Beyeh, N. K., Kalenius, E., Ras, R. H. A., & Rissanen, K. (2016). 2-Methylresorcinarene : a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion. Chemical Communications, 52(52), 8115-8118. https://doi.org/10.1039/C6CC03289C
License
Copyright© 2016 the Authors. This is an open access article distributed under the terms of the Creative Commons Attribution License.