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An easy access to fused chromanones via rhodium catalyzed oxidative coupling of salicylaldehydes with heterobicyclic olefins

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Vijayan, A., Baiju, T. V., Jijy, E., Prakash, P., Shimi, M., Joseph, N., . . . Radhakrishnan, K. V. (2016). An easy access to fused chromanones via rhodium catalyzed oxidative coupling of salicylaldehydes with heterobicyclic olefins. Tetrahedron, 72 (27-28), 4007-4015. doi:10.1016/j.tet.2016.05.031
Published in
Tetrahedron
Authors
Vijayan, Ajesh |
Baiju, T. V. |
Jijy, E. |
Prakash, Praveen |
Shimi, M. |
Joseph, Nayana |
Pihko, Petri |
Varughese, Sunil |
Radhakrishnan, K. V.
Date
2016
Discipline
Orgaaninen kemia
Copyright
© 2016 Elsevier Ltd. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.

 
Herein we describe a detailed study on the rhodium catalyzed oxidative coupling of salicylaldehydes with heterobicyclic olefins such as diazabicyclic olefins and urea-derived bicyclic olefins. The developed method provides an ideal route to fused chromanone systems in a single synthetic step. Moreover, the scope of this methodology was extended to different oxa/aza-bridged bicyclic urea derivatives.
Publisher
Pergamon
ISSN Search the Publication Forum
0040-4020
Keywords
chromanone rhodium catalyzed diazabicyclic olefins urea derived bicyclic olefins salicylaldehyde
DOI
10.1016/j.tet.2016.05.031
URI

http://urn.fi/URN:NBN:fi:jyu-201607013429

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