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dc.contributor.authorTomyn, Stefania
dc.contributor.authorHaukka, Matti
dc.contributor.authorNedelkov, Ruslan
dc.date.accessioned2016-02-09T07:08:20Z
dc.date.available2016-02-09T07:08:20Z
dc.date.issued2012
dc.identifier.citationTomyn, S., Haukka, M., & Nedelkov, R. (2012). Diammine{N-[2-(hydroxyimino)propionyl]-N'-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ4 N,N',N'',N'''}iron(III). <em>Acta Crystallographica Section E</em>, E68 (12), m1568-m1569. <a href="http://dx.doi.org/10.1107/S160053681204826X">doi:10.1107/S160053681204826X</a> Retrieved from <a href="http://journals.iucr.org/e/journalhomepage.html">http://journals.iucr.org/e/journalhomepage.html</a>
dc.identifier.otherTUTKAID_54095
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/48687
dc.description.abstractIn the title compound, [Fe(C9H13N4O4)(NH3)2], the FeIII atom, lying on a mirror plane, is coordinated by four N atoms of a triply deprotonated tetradentate N-[2-(hydroxyimino)- propionyl]-N0 -[2-(oxidoimino)propionyl]propane-1,3-diaminide ligand in the equatorial plane and two N atoms of two ammonia molecules at the axial positions in a distorted octahedral geometry. A short intramolecular O—HO hydrogen bond between the cis-disposed oxime O atoms stabilizes the pseudo-macrocyclic configuration of the ligand. In the crystal, molecules are linked by N—HO hydrogen bonds into a three-dimensional network. The ligand has a mirror-plane symmetry. One of the methylene groups of the propane bridge is disordered over two sets of sites with equal occupancy factors.
dc.language.isoeng
dc.publisherWiley-Blackwell
dc.relation.ispartofseriesActa Crystallographica Section E
dc.relation.urihttp://journals.iucr.org/e/journalhomepage.html
dc.subject.othersingle-crystal X-ray study
dc.subject.otherdisorder in main residue
dc.titleDiammine{N-[2-(hydroxyimino)propionyl]-N'-[2-(oxidoimino)propionyl]propane-1,3-diaminido-κ4 N,N',N'',N'''}iron(III)
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201602041443
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineKemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2016-02-04T10:15:20Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerangem1568-m1569
dc.relation.issn1600-5368
dc.relation.volumeE68
dc.type.versionpublishedVersion
dc.rights.copyright© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
dc.rights.accesslevelopenAccessfi
dc.rights.urlhttp://creativecommons.org/licenses/by/2.0/uk/legalcode
dc.relation.doi10.1107/S160053681204826X


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© the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.
Except where otherwise noted, this item's license is described as © the Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence.