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dc.contributor.authorVasko, Petra
dc.contributor.authorMansikkamäki, Akseli
dc.contributor.authorFettinger, James C.
dc.contributor.authorTuononen, Heikki
dc.contributor.authorPower, Philip P.
dc.date.accessioned2015-12-02T11:28:31Z
dc.date.available2017-09-30T21:45:04Z
dc.date.issued2016
dc.identifier.citationVasko, P., Mansikkamäki, A., Fettinger, J. C., Tuononen, H., & Power, P. P. (2016). Reaction of LiArMe6 (ArMe6ArMe6 = C6H3-2,6-(C6H2-2,4,6-Me3)2) with indium(I)chloride yields three m-terphenyl stabilized mixed-valent organoindium subhalides. <i>Polyhedron</i>, <i>103, Part A</i>(January), 164-171. <a href="https://doi.org/10.1016/j.poly.2015.09.052" target="_blank">https://doi.org/10.1016/j.poly.2015.09.052</a>
dc.identifier.otherCONVID_25325630
dc.identifier.otherTUTKAID_67958
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/47959
dc.description.abstractIndium(I)chloride reacts with LiArMe6 (ArMe6 = C6H3-2,6-(C6H2-2,4,6-Me3)2) in THF to give three new mixed-valent organoindium subhalides. While the 1:1 reaction of InCl with LiArMe6 yields the known metal-rich cluster In8(ArMe6)4 (1), the use of freshly prepared LiArMe6 led to incorporation of iodide, derived from the synthesis of LiArMe6, into the structures, to afford In4(ArMe6)4I2 (2) along with minor amounts of In3(ArMe6)3I2 (3). When the same reaction was performed in 4:3 stoichiometry, the mixed-halide compound In3(ArMe6)3ClI (4) was obtained. Further increasing the chloride:aryl ligand ratio resulted in the formation of the known mixed-halide species In4(ArMe6)4Cl2I2 that can also be obtained from the reaction of InCl with in situ prepared LiArMe6 in toluene. The new compounds 2 and 4 were characterized in the solid state by X-ray crystallography and IR spectroscopy, and in solution by UV/Vis and 1H/13C{1H} NMR spectroscopies. The structural characterization of 2 and 4 was supported by electronic structure calculations at the density functional level of theory which were also performed to rationalize the cluster-type bonding in 1.
dc.language.isoeng
dc.publisherPergamon
dc.relation.ispartofseriesPolyhedron
dc.subject.otherorganoindiumhalidit
dc.subject.othermolekyyliklusterit
dc.subject.otherDFT laskut
dc.subject.otherorganoindium subhalides
dc.subject.othermolecular clusters
dc.subject.otherDFT calculations
dc.titleReaction of LiArMe6 (ArMe6ArMe6 = C6H3-2,6-(C6H2-2,4,6-Me3)2) with indium(I)chloride yields three m-terphenyl stabilized mixed-valent organoindium subhalides
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201512023883
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineFysikaalinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiainePhysical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2015-12-02T07:15:04Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange164-171
dc.relation.issn0277-5387
dc.relation.numberinseriesJanuary
dc.relation.volume103, Part A
dc.type.versionacceptedVersion
dc.rights.copyright© 2015 Elsevier Ltd. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.subject.ysoröntgenkristallografia
jyx.subject.urihttp://www.yso.fi/onto/yso/p29058
dc.relation.doi10.1016/j.poly.2015.09.052


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