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dc.contributor.authorVasko, Petra
dc.contributor.authorWang, Shuai
dc.contributor.authorTuononen, Heikki
dc.contributor.authorPower, Philip P.
dc.date.accessioned2015-11-30T09:55:04Z
dc.date.available2016-01-28T22:45:06Z
dc.date.issued2015
dc.identifier.citationVasko, P., Wang, S., Tuononen, H., & Power, P. P. (2015). Addition of Ethylene or Hydrogen to a Main-Group Metal Cluster under Mild Conditions. <i>Angewandte Chemie International Edition</i>, <i>54</i>(12), 3802-3805. <a href="https://doi.org/10.1002/anie.201411595" target="_blank">https://doi.org/10.1002/anie.201411595</a>
dc.identifier.otherCONVID_24572494
dc.identifier.otherTUTKAID_65352
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/47861
dc.description.abstractReaction of the tin cluster Sn8(Arinline image)4 (Arinline image=C6H2-2,6-(C6H3-2,4,6-Me3)2) with excess ethylene or dihydrogen at 25 °C/1 atmosphere yielded two new clusters that incorporated ethylene or hydrogen. The reaction with ethylene yielded Sn4(Arinline image)4(C2H2)5 that contained five ethylene moieties bridging four aryl substituted tin atoms and one tin–tin bond. Reaction with H2 produced a cyclic tin species of formula (Sn(H)Arinline image)4, which could also be synthesized by the reaction of {(Arinline image)Sn(μ-Cl)}2 with DIBAL-H. These reactions represent the first instances of direct reactions of isolable main-group clusters with ethylene or hydrogen under mild conditions. The products were characterized in the solid state by X-ray diffraction and IR spectroscopy and in solution by multinuclear NMR and UV/Vis spectroscopies. Density functional theory calculations were performed to explain the reactivity of the cluster.
dc.language.isoeng
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA
dc.relation.ispartofseriesAngewandte Chemie International Edition
dc.subject.othermetalliklusterit
dc.subject.otheretyleeni
dc.subject.otherpienmolekyylien aktivointi
dc.subject.otherethylene
dc.subject.othersmall molecule activation
dc.titleAddition of Ethylene or Hydrogen to a Main-Group Metal Cluster under Mild Conditions
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201511253818
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2015-11-25T13:15:35Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange3802-3805
dc.relation.issn1433-7851
dc.relation.numberinseries12
dc.relation.volume54
dc.type.versionacceptedVersion
dc.rights.copyright© 2015 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.subject.ysovety
dc.subject.ysotina
dc.subject.ysoklusterit
jyx.subject.urihttp://www.yso.fi/onto/yso/p16151
jyx.subject.urihttp://www.yso.fi/onto/yso/p15916
jyx.subject.urihttp://www.yso.fi/onto/yso/p18755
dc.relation.doi10.1002/anie.201411595


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