A σ-Donor with a Planar Six-π-Electron B2N2C2 Framework: Anionic N-Heterocyclic Carbene or Heterocyclic Terphenyl Anion?
Abstract
NB! The anionic ligand 2 was synthesized through deprotonation of a planar, formally zwitterionic diazadiborine precursor, isolated as a lithium salt, and structurally characterized. According to experimental evidence and theoretical calculations, 2 can be considered as an intermediate between two classical classes of ligands: N-heterocyclic carbenes 1 and terphenyls 3.
Main Authors
Format
Articles
Research article
Published
2006
Series
Subjects
Publication in research information system
Publisher
Wiley
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201511253813Use this for linking
Review status
Peer reviewed
ISSN
1433-7851
DOI
https://doi.org/10.1002/anie.200601229
Language
English
Published in
Angewandte Chemie, International Edition
Citation
- Forster, T., Krahulic, K., Tuononen, H., McDonald, R., Parvez, M., & Roesler, R. (2006). A σ-Donor with a Planar Six-π-Electron B2N2C2 Framework: Anionic N-Heterocyclic Carbene or Heterocyclic Terphenyl Anion?. Angewandte Chemie, International Edition, 45(38), 6356-6359. https://doi.org/10.1002/anie.200601229
License
Copyright© 2006 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.