dc.contributor.author | Faust, Michelle | |
dc.contributor.author | Bryan, Aimee M. | |
dc.contributor.author | Mansikkamäki, Akseli | |
dc.contributor.author | Vasko, Petra | |
dc.contributor.author | Olmstead, Marilyn M. | |
dc.contributor.author | Tuononen, Heikki | |
dc.contributor.author | Grandjean, Fernande | |
dc.contributor.author | Long, Gary J. | |
dc.contributor.author | Power, Philip P. | |
dc.date.accessioned | 2015-11-30T07:22:13Z | |
dc.date.available | 2016-09-02T21:45:05Z | |
dc.date.issued | 2015 | |
dc.identifier.citation | Faust, M., Bryan, A. M., Mansikkamäki, A., Vasko, P., Olmstead, M. M., Tuononen, H., Grandjean, F., Long, G. J., & Power, P. P. (2015). The Instability of Ni{N(SiMe3)2}2: A Fifty Year Old Transition Metal Silylamide Mystery. <i>Angewandte Chemie International Edition</i>, <i>54</i>(44), 12914-12917. <a href="https://doi.org/10.1002/anie.201505518" target="_blank">https://doi.org/10.1002/anie.201505518</a> | |
dc.identifier.other | CONVID_24869483 | |
dc.identifier.other | TUTKAID_67037 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/47849 | |
dc.description.abstract | The characterization of the unstable NiII bis(silylamide) Ni{N(SiMe3)2}2 (1), its THF complex Ni{N(SiMe3)2}2(THF) (2), and the stable bis(pyridine) derivative trans-Ni{N(SiMe3)2}2(py)2 (3), is described. Both 1 and 2 decompose at ca. 25 °C to a tetrameric NiI species, [Ni{N(SiMe3)2}]4 (4), also obtainable from LiN(SiMe3)2 and NiCl2(DME). Experimental and computational data indicate that the instability of 1 is likely due to ease of reduction of NiII to NiI and the stabilization of 4 through dispersion forces. | |
dc.language.iso | eng | |
dc.publisher | Wiley - VCH Verlag GmbH & Co. KGaA | |
dc.relation.ispartofseries | Angewandte Chemie International Edition | |
dc.subject.other | dispersiovuorovaikutus | |
dc.subject.other | nikkelikompleksit | |
dc.subject.other | silyyliamidiligandi | |
dc.subject.other | steeriset vuorovaikutukset | |
dc.subject.other | dispersion effects | |
dc.subject.other | silylamide | |
dc.subject.other | steric effects | |
dc.title | The Instability of Ni{N(SiMe3)2}2: A Fifty Year Old Transition Metal Silylamide Mystery | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201511253814 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Fysikaalinen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Physical Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2015-11-25T13:15:19Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 12914-12917 | |
dc.relation.issn | 1433-7851 | |
dc.relation.numberinseries | 44 | |
dc.relation.volume | 54 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2015 Wiley-VCH Verlag GmbH &Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.subject.yso | magneettiset ominaisuudet | |
dc.subject.yso | magnetismi | |
dc.subject.yso | nikkeli | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p597 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p7808 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p19926 | |
dc.relation.doi | 10.1002/anie.201505518 | |
dc.type.okm | A1 | |