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dc.contributor.authorFaust, Michelle
dc.contributor.authorBryan, Aimee M.
dc.contributor.authorMansikkamäki, Akseli
dc.contributor.authorVasko, Petra
dc.contributor.authorOlmstead, Marilyn M.
dc.contributor.authorTuononen, Heikki
dc.contributor.authorGrandjean, Fernande
dc.contributor.authorLong, Gary J.
dc.contributor.authorPower, Philip P.
dc.date.accessioned2015-11-30T07:22:13Z
dc.date.available2016-09-02T21:45:05Z
dc.date.issued2015
dc.identifier.citationFaust, M., Bryan, A. M., Mansikkamäki, A., Vasko, P., Olmstead, M. M., Tuononen, H., Grandjean, F., Long, G. J., & Power, P. P. (2015). The Instability of Ni{N(SiMe3)2}2: A Fifty Year Old Transition Metal Silylamide Mystery. <i>Angewandte Chemie International Edition</i>, <i>54</i>(44), 12914-12917. <a href="https://doi.org/10.1002/anie.201505518" target="_blank">https://doi.org/10.1002/anie.201505518</a>
dc.identifier.otherCONVID_24869483
dc.identifier.otherTUTKAID_67037
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/47849
dc.description.abstractThe characterization of the unstable NiII bis(silylamide) Ni{N(SiMe3)2}2 (1), its THF complex Ni{N(SiMe3)2}2(THF) (2), and the stable bis(pyridine) derivative trans-Ni{N(SiMe3)2}2(py)2 (3), is described. Both 1 and 2 decompose at ca. 25 °C to a tetrameric NiI species, [Ni{N(SiMe3)2}]4 (4), also obtainable from LiN(SiMe3)2 and NiCl2(DME). Experimental and computational data indicate that the instability of 1 is likely due to ease of reduction of NiII to NiI and the stabilization of 4 through dispersion forces.
dc.language.isoeng
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA
dc.relation.ispartofseriesAngewandte Chemie International Edition
dc.subject.otherdispersiovuorovaikutus
dc.subject.othernikkelikompleksit
dc.subject.othersilyyliamidiligandi
dc.subject.othersteeriset vuorovaikutukset
dc.subject.otherdispersion effects
dc.subject.othersilylamide
dc.subject.othersteric effects
dc.titleThe Instability of Ni{N(SiMe3)2}2: A Fifty Year Old Transition Metal Silylamide Mystery
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201511253814
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineFysikaalinen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiainePhysical Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2015-11-25T13:15:19Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange12914-12917
dc.relation.issn1433-7851
dc.relation.numberinseries44
dc.relation.volume54
dc.type.versionacceptedVersion
dc.rights.copyright© 2015 Wiley-VCH Verlag GmbH &Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.subject.ysomagneettiset ominaisuudet
dc.subject.ysomagnetismi
dc.subject.ysonikkeli
jyx.subject.urihttp://www.yso.fi/onto/yso/p597
jyx.subject.urihttp://www.yso.fi/onto/yso/p7808
jyx.subject.urihttp://www.yso.fi/onto/yso/p19926
dc.relation.doi10.1002/anie.201505518
dc.type.okmA1


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