Extending the Series: Synthesis and Characterization of a Dicationic N-Heterocyclic Selenium Carbene Analogue
Abstract
The room-temperature reaction between the Dipp2DAB ligand, SnCl2, and SeCl4 results in the quantitative formation of a dicationic N-heterocyclic “carbenoid”. This represents the first example of a chalcogenium dication that mimics the ubiquitous Arduengo-type carbenes; however, the electronic structure is significantly different.
Main Authors
Format
Articles
Research article
Published
2006
Series
Subjects
Publication in research information system
Publisher
ACS
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201511183697Use this for linking
Review status
Peer reviewed
ISSN
0002-7863
DOI
https://doi.org/10.1021/ja064381d
Language
English
Published in
Journal of the American Chemical Society
Citation
- Dutton, J., Tuononen, H., Jennings, M., & Ragogna, P. (2006). Extending the Series: Synthesis and Characterization of a Dicationic N-Heterocyclic Selenium Carbene Analogue. Journal of the American Chemical Society, 128(39), 12624-12625. https://doi.org/10.1021/ja064381d
License
Copyright© 2006 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.