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dc.contributor.advisorRissanen, Kari
dc.contributor.advisorHaukka, Matti
dc.contributor.authorBulatova, Margarita
dc.date.accessioned2015-05-21T09:06:28Z
dc.date.available2015-05-21T09:06:28Z
dc.date.issued2015
dc.identifier.otheroai:jykdok.linneanet.fi:1474057
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/45974
dc.description.abstractFor this thesis a study of the coordination properties of biimidazole-based compounds was performed. The thesis is divided into two parts: literature part, where the chemistry and application of biimidazole and its derivatives are discussed, and experimental part, where the synthesis and coordination properties of biimidazole-based ligands are studied and discussed. The literature part contains a discussion of coordinative properties of biimidazole-derived ligands and a discussion of different types of weak interactions. Definition, nature and examples of hydrogen and different types of π-bonding were considered in detail. Due to chemical properties of biimidazole-derived compounds they have been applied in medicine, supramolecular chemistry, and coordination chemistry. A short overview of these applications presented in the literature part. The experimental part contains synthetic procedures of several biimidazole-based ligands with promising supramolecular properties. The ability of the synthesized ligands to bind d-block transition metals such as Fe(II), Zn(II), Ru(II), Ag(I), Re(III), Pt(II), Au(I) was studied. A variety of coordination frameworks were synthesized using biimidazole-based compounds. In addition, a novel coordination compound of biimidazole-based ligand and potassium iodide was synthesized and investigated.en
dc.format.extent1 verkkoaineisto (95 sivua)
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.rightsThis publication is copyrighted. You may download, display and print it for Your own personal use. Commercial use is prohibited.en
dc.rightsJulkaisu on tekijänoikeussäännösten alainen. Teosta voi lukea ja tulostaa henkilökohtaista käyttöä varten. Käyttö kaupallisiin tarkoituksiin on kielletty.fi
dc.subject.othersupramolekulaarinen kemia
dc.subject.otherbiimidazole
dc.titleSynthesis and investigation of coordinative properties of biimidazole-derived ligands
dc.identifier.urnURN:NBN:fi:jyu-201505211934
dc.type.ontasotPro gradu -tutkielmafi
dc.type.ontasotMaster’s thesisen
dc.contributor.tiedekuntaMatemaattis-luonnontieteellinen tiedekuntafi
dc.contributor.tiedekuntaFaculty of Sciencesen
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.yliopistoUniversity of Jyväskyläen
dc.contributor.yliopistoJyväskylän yliopistofi
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineOrganic Chemistryen
dc.date.updated2015-05-21T09:06:29Z
dc.rights.accesslevelopenAccessfi
dc.type.publicationmasterThesis
dc.contributor.oppiainekoodi4035
dc.subject.ysoligandit
dc.format.contentfulltext
dc.type.okmG2


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