dc.contributor.advisor | Rissanen, Kari | |
dc.contributor.advisor | Haukka, Matti | |
dc.contributor.author | Bulatova, Margarita | |
dc.date.accessioned | 2015-05-21T09:06:28Z | |
dc.date.available | 2015-05-21T09:06:28Z | |
dc.date.issued | 2015 | |
dc.identifier.other | oai:jykdok.linneanet.fi:1474057 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/45974 | |
dc.description.abstract | For this thesis a study of the coordination properties of biimidazole-based compounds was performed. The thesis is divided into two parts: literature part, where the chemistry and application of biimidazole and its derivatives are discussed, and experimental part, where the synthesis and coordination properties of biimidazole-based ligands are studied and discussed.
The literature part contains a discussion of coordinative properties of biimidazole-derived ligands and a discussion of different types of weak interactions. Definition, nature and examples of hydrogen and different types of π-bonding were considered in detail. Due to chemical properties of biimidazole-derived compounds they have been applied in medicine, supramolecular chemistry, and coordination chemistry. A short overview of these applications presented in the literature part.
The experimental part contains synthetic procedures of several biimidazole-based ligands with promising supramolecular properties. The ability of the synthesized ligands to bind d-block transition metals such as Fe(II), Zn(II), Ru(II), Ag(I), Re(III), Pt(II), Au(I) was studied. A variety of coordination frameworks were synthesized using biimidazole-based compounds. In addition, a novel coordination compound of biimidazole-based ligand and potassium iodide was synthesized and investigated. | en |
dc.format.extent | 1 verkkoaineisto (95 sivua) | |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.rights | In Copyright | en |
dc.subject.other | supramolekulaarinen kemia | |
dc.subject.other | biimidazole | |
dc.title | Synthesis and investigation of coordinative properties of biimidazole-derived ligands | |
dc.type | master thesis | |
dc.identifier.urn | URN:NBN:fi:jyu-201505211934 | |
dc.type.ontasot | Pro gradu -tutkielma | fi |
dc.type.ontasot | Master’s thesis | en |
dc.contributor.tiedekunta | Matemaattis-luonnontieteellinen tiedekunta | fi |
dc.contributor.tiedekunta | Faculty of Sciences | en |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.yliopisto | University of Jyväskylä | en |
dc.contributor.yliopisto | Jyväskylän yliopisto | fi |
dc.contributor.oppiaine | Orgaaninen kemia | fi |
dc.contributor.oppiaine | Organic Chemistry | en |
dc.date.updated | 2015-05-21T09:06:29Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_bdcc | |
dc.rights.accesslevel | openAccess | fi |
dc.type.publication | masterThesis | |
dc.contributor.oppiainekoodi | 4035 | |
dc.subject.yso | ligandit | |
dc.format.content | fulltext | |
dc.rights.url | https://rightsstatements.org/page/InC/1.0/ | |
dc.type.okm | G2 | |