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Efficient regio- and stereoselective access to novel fluorinated β-aminocyclohexanecarboxylates

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Kiss, L., Nonn, M., Sillanpää, R., Fustero, S., & Fülöp, F. (2013). Efficient regio- and stereoselective access to novel fluorinated β-aminocyclohexanecarboxylates. Beilstein Journal of Organic Chemistry, 9, 1164-1169. https://doi.org/10.3762/bjoc.9.130
Published in
Beilstein Journal of Organic Chemistry
Authors
Kiss, Loránd |
Nonn, Melinda |
Sillanpää, Reijo |
Fustero, Santos |
Fülöp, Ferenc
Date
2013
Discipline
Epäorgaaninen ja analyyttinen kemiaInorganic and Analytical Chemistry

 
A regio- and stereoselective method has been developed for the synthesis of novel fluorinated 2-aminocyclohexanecarboxylic acid derivatives with the fluorine attached to position 4 of the ring. The synthesis starts from either cis- or trans-β-aminocyclohex-4-enecarboxylic acids and involves regio- and stereoselective transformation of the ring C–C double bond through iodooxazine formation and hydroxylation, followed by hydroxy–fluorine or oxo–fluorine exchange.
Publisher
Beilstein - Institut zur Foerderung der Chemischen Wissenschaften
ISSN Search the Publication Forum
1860-5397
Keywords
epoxidation fluorination hydroxylation stereoselective reaction aminohapot

Original source
http://www.beilstein-journals.org/bjoc/home/home.htm

DOI
https://doi.org/10.3762/bjoc.9.130
URI

http://urn.fi/URN:NBN:fi:jyu-201401211090

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/23006295

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  • Matemaattis-luonnontieteellinen tiedekunta [5428]

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