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dc.contributor.authorKontkanen, Maija-Liisa
dc.contributor.authorTuikka, Matti
dc.contributor.authorKinnunen, Niko M.
dc.contributor.authorSuvanto, Sari
dc.contributor.authorHaukka, Matti
dc.date.accessioned2013-05-22T05:57:50Z
dc.date.available2013-05-22T05:57:50Z
dc.date.issued2013fi
dc.identifier.citationKontkanen, M-L., Tuikka, M, Kinnunen, M. N., Suvanto, S. & Haukka, M. (2013). Hydroformylation of 1-Hexene over Rh/Nano-Oxide Catalysts. Catalysts, 3 (1), 324-337. doi:10.3390/catal3010324 Retrieved from http://www.mdpi.com/2073-4344/3/1/324fi
dc.identifier.otherTUTKAID_56570
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/41532
dc.description.abstractThe effect of nanostructured supports on the activity of Rh catalysts was studied by comparing the catalytic performance of nano- and bulk-oxide supported Rh/ZnO, Rh/SiO₂ and Rh/TiO₂ systems in 1-hexene hydroformylation. The highest activity with 100% total conversion and 96% yield of aldehydes was obtained with the Rh/nano-ZnO catalyst. The Rh/nano-ZnO catalyst was found to be more stable and active than the corresponding rhodium catalyst supported on bulk ZnO. The favorable morphology of Rh/nano-ZnO particles led to an increased metal content and an increased number of weak acid sites compared to the bulk ZnO supported catalysts. Both these factors favored the improved catalytic performance. Improvements of catalytic properties were obtained also with the nano-SiO₂ and nano-TiO₂ supports in comparison with the bulk supports. All of the catalysts were characterized by scanning electron microscope (SEM), inductively coupled plasma mass spectrometry (ICP-MS), BET, powder X-ray diffraction (PXRD) and NH3- temperature-programmed desorption (TPD).fi
dc.language.isoeng
dc.publisherMDPI AG
dc.relation.ispartofseriesCatalysts
dc.relation.urihttp://www.mdpi.com/2073-4344/3/1/324
dc.subject.otherkatalyysifi
dc.subject.otherhydroformylointifi
dc.subject.othernano-oxiditfi
dc.subject.otherrodiumfi
dc.subject.othercatalysisfi
dc.subject.otherhydroformylation nano-oxidefi
dc.subject.otherrhodiumfi
dc.titleHydroformylation of 1-Hexene over Rh/Nano-Oxide Catalystsfi
dc.identifier.urnURN:NBN:fi:jyu-201305221744
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2013-05-22T03:30:12Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange324-337
dc.relation.issn2073-4344
dc.relation.numberinseries1
dc.relation.volume3
dc.type.versionpublishedVersion
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.3390/catal3010324


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