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dc.contributor.authorNauha, Elisa
dc.contributor.authorSaxell, Heidi
dc.contributor.authorNissinen, Maija
dc.contributor.authorKolehmainen, Erkki
dc.contributor.authorSchäfer, Ansgar
dc.contributor.authorSchlecker, Rainer
dc.date.accessioned2011-11-08T07:10:56Z
dc.date.available2011-11-08T07:10:56Z
dc.date.issued2009
dc.identifier.citationNauha, E., Saxell, H., Nissinen, M., Kolehmainen, E., Schäfer, A., & Schlecker, R. (2009). Polymorphism and versatile solvate formation of thiophanate-methyl. <i>CrystEngComm</i>, <i>11</i>, 2536-2547. <a href="https://doi.org/10.1039/B905511H" target="_blank">https://doi.org/10.1039/B905511H</a>
dc.identifier.otherCONVID_18940705
dc.identifier.otherTUTKAID_36678
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/36906
dc.description.abstractThe polymorphism of a fungicide, thiophanate-methyl (TM), was investigated with conventional solvent screening methods. Two polymorphs, the thermodynamically most stable form I and the less stable form II, were found. TM was also found to crystallize as a plethora of different solvates which produced mostly form II upon desolvation. The structures of form I and form II and the fourteen discovered solvates were solved by single crystal X-ray diffraction. The most stable forms were further characterized by powder diffraction, thermoanalytical (TG/DTA, DSC and thermomicroscopy) and spectroscopic (IR, Raman, ¹³C CP/MAS NMR) methods.
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesCrystEngComm
dc.relation.urihttp://www.rsc.org/Publishing/Journals/CE/article.asp?doi=b905511h
dc.subject.otherpolymorfia
dc.subject.othersolvaatti
dc.subject.otherkidemuoto
dc.subject.otherpolymorphism
dc.subject.othersolvate
dc.subject.othercrystal form
dc.titlePolymorphism and versatile solvate formation of thiophanate-methyl
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-2011110811638
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2011-11-08T04:30:13Z
dc.contributor.publisherRoyal Society of Chemistry
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange2536-2547
dc.relation.volume11
dc.type.versionacceptedVersion
dc.rights.copyright© The Royal Society of Chemistry. This is an electronic final draft version of the article whose final and definitive form has been published in CrystEngcomm.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1039/B905511H
dc.type.okmA1


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