2-Methyl-4-phenyl-3,4-dihydroquinazoline
Abstract
The title compound, C15H14N2, was formed during the lithiation of 2-methylquinazoline with phenyllithium followed by hydrolysis of the intermediate lithium 2-methyl-4-phenyl-4H-quinazolin-3-ide. NMR spectra as well as single-crystal X-ray structural data indicate that the reaction product to have the same structure in chloroform solution as in the crystalline state. The phenyl substituent is twisted out of the plane of the 3,4-dihydroquinazoline ring system by 86.47 (7)°. In the crystal, intermolecular N-HN interactions connect the molecules into infinite chains.
Main Authors
Format
Articles
Research article
Published
2011
Series
Subjects
Publication in research information system
Publisher
International Union of Crystallography
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201142810693Käytä tätä linkitykseen.
Review status
Peer reviewed
ISSN
1600-5368
DOI
https://doi.org/10.1107/S1600536811009664
Language
English
Published in
Acta Crystallographica, Section E, Structure Reports Online
Citation
- Valkonen, A., Kolehmainen, E., Zakrzewska, A., Skotnicka, A., & Gawinecki, R. (2011). 2-Methyl-4-phenyl-3,4-dihydroquinazoline. Acta Crystallographica, Section E, Structure Reports Online, 67 (4), o923-o924. doi:10.1107/S1600536811009664
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