Synthesis of Both Ionic Species of Ammonium Dithiocarbamate Derived Cholic Acid Moieties

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dc.contributor.author Koivukorpi, Juha
dc.contributor.author Kolehmainen, Erkki
dc.date.accessioned 2012-11-02T08:58:37Z
dc.date.available 2012-11-02T08:58:37Z
dc.date.issued 2011
dc.identifier.citation Koivukorpi, J., & Kolehmainen, E. (2011). Synthesis of Both Ionic Species of Ammonium Dithiocarbamate Derived Cholic Acid Moieties. Molecules, 16 (8), 6306-6312. doi:10.3390/molecules16086306 Retrieved from http://www.mdpi.com/journal/molecules/
dc.identifier.issn 1420-3049
dc.identifier.uri http://hdl.handle.net/123456789/40156
dc.description.abstract The reaction of 3-aminopropylamide of cholic acid with CS₂ produced a bile acid derivative of dithiocarbamic acid which further formed an ammonium salt with another molecule of 3-aminopropylamide of cholic acid. The cationic 3-ammonium propylamide of cholic acid did not react further with CS₂ and the formed salt was stable in the reaction mixture, even when excess CS₂ was used. When the reaction was carried out in the presence of aqueous sodium hydroxide, only the bile acid derivative of sodium dithiocarbamate was formed. The dithiocarbamate derivatives were characterized by ¹H- and ¹³C-NMR spectroscopy and ESI-TOF mass spectrometry. fi
dc.language.iso eng
dc.publisher MDPI
dc.relation.ispartofseries Molecules
dc.relation.uri http://www.mdpi.com/journal/molecules
dc.rights © 2011 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license.
dc.rights.uri http://creativecommons.org/licenses/by/3.0/
dc.subject.other cholic acid en
dc.subject.other dithiocarbamate en
dc.subject.other dithiocarbamate en
dc.subject.other steroid en
dc.subject.other NMR spectroscopy en
dc.subject.other amine en
dc.title Synthesis of Both Ionic Species of Ammonium Dithiocarbamate Derived Cholic Acid Moieties
dc.type Article en
dc.identifier.urn URN:NBN:fi:jyu-201211022843
dc.subject.kota 116
dc.contributor.laitos Department of Chemistry en
dc.contributor.laitos Kemian laitos fi
dc.type.uri http://purl.org/eprint/type/JournalArticle
dc.identifier.doi 10.3390/molecules16086306
dc.description.version Publisher's PDF
eprint.status http://purl.org/eprint/type/status/PeerReviewed

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