Packing incentives and a reliable N–H···N pyridine synthon in co-crystallization of bipyridines with two agrochemical actives

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dc.contributor.author Nauha, Elisa
dc.contributor.author Kolehmainen, Erkki
dc.contributor.author Nissinen, Maija
dc.date.accessioned 2011-11-16T05:35:21Z
dc.date.available 2012-09-01T21:45:03Z
dc.date.issued 2011
dc.identifier.citation Nauha, E., Kolehmainen, E. & Nissinen, M. (2011). Packing incentives and a reliable N–H···N pyridine synthon in co-crystallization of bipyridines with two agrochemical actives. CrystEngComm, 13 (21), 6531-6537. doi:10.1039/C1CE05730H fi
dc.identifier.issn 1466-8033
dc.identifier.other TUTKAID_47525
dc.identifier.uri http://hdl.handle.net/123456789/36953
dc.description.abstract The co-crystallization of agrochemical actives thiophanate-methyl and thiophanate-ethyl with 2,2′-bipyridine, 4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane was investigated with conventional crystallization, the slurry method and liquid-assisted grinding. Co-crystals of both thiophanates with all bipyridines were found and the structures solved with single crystal X-ray diffraction. Whereas the 2,2′-bipyridine co-crystals seem to form because of a combination of weak interactions, and in the case of the thiophanate-methyl, partly because of close packing incentives, the 4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane co-crystals form mainly because of a favourable N–H···N–pyridine hydrogen bonding synthon.
dc.language.iso eng
dc.publisher Royal Society of Chemistry
dc.relation.ispartof CrystEngComm
dc.rights © The Royal Society of Chemistry 2011. This is an electronic final draft version of an article whose final and definitive form has been published in CrystEngComm by RSC.
dc.subject.other yhteiskide fi
dc.subject.other supramolekyyli fi
dc.subject.other röntgen diffraktio fi
dc.subject.other cocrystal en
dc.subject.other co-crystal en
dc.subject.other supramolecular synthon en
dc.subject.other X-ray diffraction en
dc.title Packing incentives and a reliable N–H···N pyridine synthon in co-crystallization of bipyridines with two agrochemical actives
dc.type Article en
dc.identifier.urn URN:NBN:fi:jyu-2011111511684
dc.subject.kota 116
dc.contributor.laitos Department of Chemistry en
dc.contributor.laitos Kemian laitos fi
dc.contributor.oppiaine orgaaninen kemia fi
jyx.tutka.volyme 13
jyx.tutka.mnumber 21
jyx.tutka.pagetopage 6531-6537
dc.type.uri http://purl.org/eprint/type/JournalArticle
dc.identifier.doi 10.1039/C1CE05730H
dc.date.updated 2011-11-15T04:30:10Z
dc.description.version Final draft
eprint.status http://purl.org/eprint/type/status/PeerReviewed

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