Packing incentives and a reliable N–H···N pyridine synthon in co-crystallization of bipyridines with two agrochemical actives

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Show simple item record Nauha, Elisa Kolehmainen, Erkki Nissinen, Maija 2011-11-16T05:35:21Z 2012-09-01T21:45:03Z 2011
dc.identifier.citation Nauha, E., Kolehmainen, E., & Nissinen, M. (2011). Packing incentives and a reliable N–H...N–pyridine synthon in co-crystallization of bipyridines with two agrochemical actives. <em>CrystEngComm</em>, 13 (21), 6531-6537. <a href="">doi:10.1039/C1CE05730H</a> fi
dc.identifier.issn 1466-8033
dc.identifier.other TUTKAID_47525
dc.description.abstract The co-crystallization of agrochemical actives thiophanate-methyl and thiophanate-ethyl with 2,2′-bipyridine, 4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane was investigated with conventional crystallization, the slurry method and liquid-assisted grinding. Co-crystals of both thiophanates with all bipyridines were found and the structures solved with single crystal X-ray diffraction. Whereas the 2,2′-bipyridine co-crystals seem to form because of a combination of weak interactions, and in the case of the thiophanate-methyl, partly because of close packing incentives, the 4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane co-crystals form mainly because of a favourable N–H···N–pyridine hydrogen bonding synthon.
dc.language.iso eng
dc.publisher Royal Society of Chemistry
dc.relation.ispartofseries CrystEngComm
dc.rights © The Royal Society of Chemistry 2011. This is an electronic final draft version of an article whose final and definitive form has been published in CrystEngComm by RSC.
dc.rights openAccess fi
dc.subject.other cocrystal en
dc.subject.other co-crystal en
dc.subject.other supramolecular synthon en
dc.subject.other X-ray diffraction en
dc.subject.other yhteiskide fi
dc.subject.other supramolekyyli fi
dc.subject.other röntgen diffraktio fi
dc.title Packing incentives and a reliable N–H···N pyridine synthon in co-crystallization of bipyridines with two agrochemical actives
dc.type Article
dc.identifier.urn URN:NBN:fi:jyu-2011111511684
dc.subject.kota 116
dc.contributor.laitos Kemian laitos fi
dc.contributor.laitos Department of Chemistry en
dc.contributor.oppiaine orgaaninen kemia fi
dc.identifier.volume 13
dc.identifier.issue 21
jyx.tutka.pagetopage 6531-6537
dc.identifier.doi 10.1039/C1CE05730H 2011-11-15T04:30:10Z
dc.description.version Final Draft
dc.type.coar journal article
dc.description.reviewstatus peerReviewed
dc.format.pagerange 6531-6537
dc.relation.issn 1466-8033
dc.relation.issue 21
dc.relation.volume 13
dc.type.version acceptedVersion

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