Polymorphism and versatile solvate formation of thiophanate-methyl

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dc.contributor.author Nauha, Elisa
dc.contributor.author Saxell, Heidi
dc.contributor.author Nissinen, Maija
dc.contributor.author Kolehmainen, Erkki
dc.contributor.author Schäfer, Ansgar
dc.contributor.author Schlecker, Rainer
dc.date.accessioned 2011-11-08T07:10:56Z
dc.date.available 2011-11-08T07:10:56Z
dc.date.issued 2009
dc.identifier.citation Nauha, E., Saxell, H., Nissinen, M., Kolehmainen, E., Schäfer, A. & Schlecker, R. (2009). Polymorphism and versatile solvate formation of thiophanate-methyl. CrystEngComm, 11, 2536-2547. Retrieved from http://www.rsc.org/Publishing/Journals/CE/article.asp?doi=b905511h
dc.identifier.other TUTKAID_36678
dc.identifier.uri http://hdl.handle.net/123456789/36906
dc.description.abstract The polymorphism of a fungicide, thiophanate-methyl (TM), was investigated with conventional solvent screening methods. Two polymorphs, the thermodynamically most stable form I and the less stable form II, were found. TM was also found to crystallize as a plethora of different solvates which produced mostly form II upon desolvation. The structures of form I and form II and the fourteen discovered solvates were solved by single crystal X-ray diffraction. The most stable forms were further characterized by powder diffraction, thermoanalytical (TG/DTA, DSC and thermomicroscopy) and spectroscopic (IR, Raman, ¹³C CP/MAS NMR) methods.
dc.language.iso eng
dc.relation.ispartof CrystEngComm
dc.relation.uri http://www.rsc.org/Publishing/Journals/CE/article.asp?doi=b905511h
dc.rights © The Royal Society of Chemistry. This is an electronic final draft version of the article whose final and definitive form has been published in CrystEngcomm.
dc.subject.other polymorfia fi
dc.subject.other solvaatti fi
dc.subject.other kidemuoto fi
dc.subject.other polymorphism en
dc.subject.other solvate en
dc.subject.other crystal form en
dc.title Polymorphism and versatile solvate formation of thiophanate-methyl
dc.type Article en
dc.identifier.urn URN:NBN:fi:jyu-2011110811638
dc.contributor.laitos Kemian laitos
dc.contributor.oppiaine Department of Chemistry en
dc.contributor.oppiaine orgaaninen kemia fi
jyx.tutka.volyme 11
jyx.tutka.pagetopage 2536-2547
dc.type.uri http://purl.org/eprint/type/SubmittedJournalArticle
dc.identifier.doi DOI:10.1039/B905511H
dc.date.updated 2011-11-08T04:30:13Z
dc.contributor.publisher Royal Society of Chemistry
eprint.status http://purl.org/eprint/type/status/PeerReviewed

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